Thermodynamics of mixtures with strongly negative deviations from Raoult’s law. XVII. Permittivities and refractive indices for alkan-1-ol + N,N-diethylethanamine systems at (293.15–303.15) K. Application of the Kirkwood-Fröhlich model

2020 ◽  
Vol 141 ◽  
pp. 105937 ◽  
Author(s):  
Fernando Hevia ◽  
Juan Antonio González ◽  
Ana Cobos ◽  
Isaías García de la Fuente ◽  
L.F. Sanz

A general formula has been obtained for the number of distinct arrangements of a mixture of any number of different types of molecules each with its own geometric properties. From this are deduced the thermodynamic properties of such mixtures when the energies of mixing are zero. In particular, the generalization of Raoult’s law has been obtained. The technique used is considerably simpler than that previously applied to problems of this type.


2001 ◽  
Vol 190 (1-2) ◽  
pp. 113-125 ◽  
Author(s):  
S Villa ◽  
N Riesco ◽  
I Garcı́a de la Fuente ◽  
J.A González ◽  
J.C Cobos

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