Thermodynamics of mixtures with strongly negative deviations from Raoult’s law

2001 ◽  
Vol 190 (1-2) ◽  
pp. 113-125 ◽  
Author(s):  
S Villa ◽  
N Riesco ◽  
I Garcı́a de la Fuente ◽  
J.A González ◽  
J.C Cobos

2021 ◽  
Vol 157 ◽  
pp. 106395
Author(s):  
Luis Felipe Sanz ◽  
Juan Antonio González ◽  
Isaías García de la Fuente ◽  
José Carlos Cobos ◽  
Fernando Hevia


A general formula has been obtained for the number of distinct arrangements of a mixture of any number of different types of molecules each with its own geometric properties. From this are deduced the thermodynamic properties of such mixtures when the energies of mixing are zero. In particular, the generalization of Raoult’s law has been obtained. The technique used is considerably simpler than that previously applied to problems of this type.



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