Thermodynamics of mixtures with strongly negative deviations from Raoult's law Part 2. Application of the DISQUAC model to mixtures of CHCl3 or CH2Cl2 with oxaalkanes. Comparison with Dortmund UNIFAC results

1999 ◽  
Vol 1 (2) ◽  
pp. 275-283 ◽  
Author(s):  
Juan Antonio González ◽  
Isías García de la Fuente ◽  
Jose´ Carlos Cobos

2021 ◽  
Vol 157 ◽  
pp. 106395
Author(s):  
Luis Felipe Sanz ◽  
Juan Antonio González ◽  
Isaías García de la Fuente ◽  
José Carlos Cobos ◽  
Fernando Hevia


A general formula has been obtained for the number of distinct arrangements of a mixture of any number of different types of molecules each with its own geometric properties. From this are deduced the thermodynamic properties of such mixtures when the energies of mixing are zero. In particular, the generalization of Raoult’s law has been obtained. The technique used is considerably simpler than that previously applied to problems of this type.



2001 ◽  
Vol 190 (1-2) ◽  
pp. 113-125 ◽  
Author(s):  
S Villa ◽  
N Riesco ◽  
I Garcı́a de la Fuente ◽  
J.A González ◽  
J.C Cobos


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