High-resolution Raman spectroscopy of the ν1 region and Raman–Raman double resonance spectroscopy of the 2ν1−ν1 band of 32SF6 and 34SF6. Determination of the equilibrium bond length of sulfur hexafluoride

2004 ◽  
Vol 228 (2) ◽  
pp. 392-400 ◽  
Author(s):  
V. Boudon ◽  
J.L. Doménech ◽  
D. Bermejo ◽  
H. Willner
Keyword(s):  
Raman Spectroscopy ◽  
High Resolution ◽  
Bond Length ◽  
Sulfur Hexafluoride ◽  
Double Resonance ◽  
Resonance Spectroscopy ◽  
Equilibrium Bond Length ◽  
Double Resonance Spectroscopy

High resolution double‐resonance spectroscopy on Rydberg states of CO

1993 ◽  
Vol 99 (8) ◽  
pp. 5701-5711 ◽  
Author(s):  
Marcel Drabbels ◽  
Johannes Heinze ◽  
J. J. ter Meulen ◽  
W. Leo Meerts
Keyword(s):  
High Resolution ◽  
Double Resonance ◽  
Rydberg States ◽  
Resonance Spectroscopy ◽  
Double Resonance Spectroscopy

The distortion moment spectrum of GeH4: the microwave Q branch

1979 ◽  
Vol 57 (4) ◽  
pp. 593-600 ◽  
Author(s):  
R. H. Kagann ◽  
I. Ozier ◽  
G. A. McRae ◽  
M. C. L. Gerry
Keyword(s):  
High Resolution ◽  
Least Squares ◽  
Double Resonance ◽  
Complete Analysis ◽  
Resonance Spectroscopy ◽  
Centrifugal Distortion ◽  
Double Resonance Spectroscopy ◽  
The Absolute ◽  
Centrifugal Distortion Constants ◽  
Single Set

Ten pure rotational Q-branch transitions of the distortion moment spectrum of GeH4 have been measured between 9 and 23 GHz. They were observed in a conventional Stark modulated spectrometer modified to have a sensitivity of 1 × 10−11 cm−1. No Ge isotope splitting was observed in the spectrum. The spectrum was analysed in terms of a single set of six tensor centrifugal distortion constants DT, H4T, H6T, L4T, L6T, and L8T. The results were found to predict accurately transitions previously reported from infrared–microwave double resonance spectroscopy, and a complete analysis using both sets of data was carried out. The results are (in hertz): DT = 67 775.54 ± 0.86; H4T = −5.3827 ± 0.0055; H6T = 2.9693 ± 0.0019; L4T = (3.996 ± 0.088) × 10−4; L6T = −(4.122 ± 0.050) × 10−4; L8T = −(8.01 ± 0.14) × 10−4. The errors here are the standard deviations obtained from the least-squares analysis; estimates of the absolute errors are also given. For possible application in other high resolution studies, the constants have been used to calculate all tensor splittings for J ≤ 20.

High-resolution double-resonance spectroscopy of 2ν_3 ← ν_3 transitions in SF_6

1981 ◽  
Vol 6 (2) ◽  
pp. 93 ◽  
Author(s):  
Chris W. Patterson ◽  
Peter F. Moulton ◽  
A. Mooradian ◽  
Robin S. McDowell
Keyword(s):  
High Resolution ◽  
Double Resonance ◽  
Resonance Spectroscopy ◽  
Double Resonance Spectroscopy
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