(La0.2Ce0.2Nd0.2Sm0.2Eu0.2)PO4: A high-entropy rare-earth phosphate monazite ceramic with low thermal conductivity and good compatibility with Al2O3

2019 ◽  
Vol 35 (12) ◽  
pp. 2892-2896 ◽  
Author(s):  
Zifan Zhao ◽  
Heng Chen ◽  
Huimin Xiang ◽  
Fu-Zhi Dai ◽  
Xiaohui Wang ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Rare Earth ◽  
Low Thermal Conductivity ◽  
High Entropy ◽  
Rare Earth Phosphate

scholarly journals High-entropy (Nd0.2Sm0.2Eu0.2Y0.2Yb0.2)4Al2O9 with good high temperature stability, low thermal conductivity and anisotropic thermal expansivity

2020 ◽  
Author(s):  
Zifan Zhao ◽  
Huimin Xiang ◽  
Heng Chen ◽  
Fu-zhi Dai ◽  
Xiaohui Wang ◽  
...  
Keyword(s):  
Phase Transition ◽  
Thermal Conductivity ◽  
Thermal Expansion ◽  
Rare Earth ◽  
High Temperature ◽  
Phase Stability ◽  
Temperature Phase ◽  
Low Thermal Conductivity ◽  
High Entropy ◽  
Anisotropic Thermal Expansion

Abstract The critical requirements for the environmental barrier coating (EBC) materials of silicon-based ceramic matrix composites (CMCs) including good tolerance to harsh environments, thermal expansion match with the interlayer mullite, good high-temperature phase stability and low thermal conductivity. Cuspidine-structured rare-earth aluminates RE4Al2O9 have been considered as candidates of EBCs for their superior mechanical and thermal properties, but the phase transition at high temperatures is a notable drawback of these materials. To suppress the phase transition and improve the phase stability, a novel cuspidine-structured rare-earth aluminate solid solution (Nd0.2Sm0.2Eu0.2Y0.2Yb0.2)4Al2O9 was designed and successfully synthesized inspired by entropy stabilization effect of high entropy ceramics. The as-synthesized (Nd0.2Sm0.2Eu0.2Y0.2Yb0.2)4Al2O9 exhibits close thermal expansion coefficient (6.96×10-6 /K at 300-1473 K) to that of mullite, good phase stability from 300 K to 1473 K, and low thermal conductivity (1.50 W·m-1·K-1 at room temperature). In addition, strong anisotropic thermal expansion has been observed compared to Y4Al2O9 and Yb4Al2O9. The mechanism for low thermal conductivity is attributed to the lattice distortion and mass difference of the constituent atoms while the anisotropic thermal expansion is due to the anisotropic chemical bonding enhanced by the large size rare earth cations.

Rare-earth-tantalate high-entropy ceramics with sluggish grain growth and low thermal conductivity

2021 ◽  
Author(s):  
Chen Li ◽  
Bin Meng ◽  
Sining Fan ◽  
Xinyu Ping ◽  
Congcong Fang ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Rare Earth ◽  
Grain Growth ◽  
Low Thermal Conductivity ◽  
High Entropy

scholarly journals High-entropy (Nd0.2Sm0.2Eu0.2Y0.2Yb0.2)4Al2O9 with good high temperature stability, low thermal conductivity and anisotropic thermal expansivity

2020 ◽  
Author(s):  
Zifan Zhao ◽  
Huimin Xiang ◽  
Heng Chen ◽  
Fu-zhi Dai ◽  
Xiaohui Wang ◽  
...  
Keyword(s):  
Phase Transition ◽  
Thermal Conductivity ◽  
Thermal Expansion ◽  
Rare Earth ◽  
High Temperature ◽  
Phase Stability ◽  
Temperature Phase ◽  
Low Thermal Conductivity ◽  
High Entropy ◽  
Anisotropic Thermal Expansion

Abstract The critical requirements for the environmental barrier coating (EBC) materials of silicon-based ceramic matrix composites (CMCs) including good tolerance to harsh environments, thermal expansion match with the interlayer mullite, good high-temperature phase stability and low thermal conductivity. Cuspidine-structured rare-earth aluminates RE4Al2O9 have been considered as candidates of EBCs for their superior mechanical and thermal properties, but the phase transition at high temperatures is a notable drawback of these materials. To suppress the phase transition and improve the phase stability, a novel cuspidine-structured rare-earth aluminate solid solution (Nd0.2Sm0.2Eu0.2Y0.2Yb0.2)4Al2O9 was designed and successfully synthesized inspired by entropy stabilization effect of high entropy ceramics. The as-synthesized (Nd0.2Sm0.2Eu0.2Y0.2Yb0.2)4Al2O9 exhibits close thermal expansion coefficient (6.96×10-6 /K at 300-1473 K) to that of mullite, good phase stability from 300 K to 1473 K, and low thermal conductivity (1.50 W·m-1·K-1 at room temperature). In addition, strong anisotropic thermal expansion has been observed compared to Y4Al2O9 and Yb4Al2O9. The mechanism for low thermal conductivity is attributed to the lattice distortion and mass difference of the constituent atoms while the anisotropic thermal expansion is due to the anisotropic chemical bonding enhanced by the large size rare earth cations.

scholarly journals High-entropy (Nd0.2Sm0.2Eu0.2Y0.2Yb0.2)4Al2O9 with good high temperature stability, low thermal conductivity, and anisotropic thermal expansivity

2020 ◽  
Vol 9 (5) ◽  
pp. 595-605
Author(s):  
Zifan Zhao ◽  
Huimin Xiang ◽  
Heng Chen ◽  
Fu-Zhi Dai ◽  
Xiaohui Wang ◽  
...  
Keyword(s):  
Phase Transition ◽  
Thermal Conductivity ◽  
Thermal Expansion ◽  
Rare Earth ◽  
High Temperature ◽  
Phase Stability ◽  
Temperature Phase ◽  
Low Thermal Conductivity ◽  
High Entropy ◽  
Anisotropic Thermal Expansion

Abstract The critical requirements for the environmental barrier coating (EBC) materials of silicon-based ceramic matrix composites (CMCs) include good tolerance to harsh environments, thermal expansion matches with the interlayer mullite, good high-temperature phase stability, and low thermal conductivity. Cuspidine-structured rare-earth aluminates RE4Al2O9 have been considered as candidates of EBCs for their superior mechanical and thermal properties, but the phase transition at high temperatures is a notable drawback of these materials. To suppress the phase transition and improve the phase stability, a novel cuspidine-structured rare-earth aluminate solid solution (Nd0.2Sm0.2Eu0.2Y0.2Yb0.2)4Al2O9 was designed and successfully synthesized inspired by entropy stabilization effect of high-entropy ceramics (HECs). The as-synthesized HE (Nd0.2Sm0.2Eu0.2Y0.2Yb0.2)4Al2O9 exhibits a close thermal expansion coefficient (6.96×10-6 K-1 at 300–1473 K) to that of mullite, good phase stability from 300 to 1473 K, and low thermal conductivity (1.50 W·m–1·K–1 at room temperature). In addition, strong anisotropic thermal expansion has been observed compared to Y4Al2O9 and Yb4Al2O9. The mechanism for low thermal conductivity is attributed to the lattice distortion and mass difference of the constituent atoms, and the anisotropic thermal expansion is due to the anisotropic chemical bonding enhanced by the large size rare-earth cations.

scholarly journals High-entropy pyrochlores with low thermal conductivity for thermal barrier coating materials

2019 ◽  
Vol 8 (4) ◽  
pp. 576-582 ◽  
Author(s):  
Fei Li ◽  
Lin Zhou ◽  
Ji-Xuan Liu ◽  
Yongcheng Liang ◽  
Guo-Jun Zhang
Keyword(s):  
Thermal Conductivity ◽  
Thermal Barrier Coating ◽  
Thermal Barrier ◽  
Coating Materials ◽  
Low Thermal Conductivity ◽  
High Entropy ◽  
Barrier Coating

A novel high-entropy monoboride (Mo0.2Ta0.2Ni0.2Cr0.2W0.2)B with superhardness and low thermal conductivity

2020 ◽  
Vol 46 (17) ◽  
pp. 26626-26631
Author(s):  
Pengbo Zhao ◽  
Jinpeng Zhu ◽  
Yilin Zhang ◽  
Gang Shao ◽  
Hailong Wang ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Low Thermal Conductivity ◽  
High Entropy
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