Pentacoordinated and hexacoordinated silicon cations in a potassium silicate glass: Effects of pressure and temperature

2019 ◽  
Vol 505 ◽  
pp. 234-240 ◽  
Author(s):  
Jonathan F. Stebbins ◽  
Saurav Bista
2005 ◽  
Vol 351 (12-13) ◽  
pp. 1133-1138 ◽  
Author(s):  
Ondrej Gedeon ◽  
Jan Macháček ◽  
Marek Liška

2005 ◽  
Vol 351 (19-20) ◽  
pp. 1665-1674 ◽  
Author(s):  
J. Zemek ◽  
P. Jiricek ◽  
O. Gedeon ◽  
B. Lesiak ◽  
A. Jozwik

2016 ◽  
Vol 702 ◽  
pp. 125-129
Author(s):  
Peter Šimurka ◽  
Jozef Kraxner ◽  
Peter Vrábel ◽  
Tomáš Paučo

Al2O3 - ZrO2 - SiO2 refractory corrosion in barium soda lime potassium silicate glass melt have been studied. The composition of glass phase of unused AZS and the concentration profiles of the principal oxides in the glass phases of corroded AZS materials were determined. The refractory samples have been taken from the melting parts of a furnace after production termination as well as from the material where the laboratory static corrosion tests have been conducted. SEM and EDX analysis have been provided on the samples located in the part above and below the metal line corrosion.The corrosion mechanism of refractories in glass melt consists of diffusion of alkalis (Na, K, Ca, Ba) from the glass melt into the refractory, dissolution of the Al2O3 and ZrO2 in the glass phase, diffusion of Zr and Al from the refractory into the glass melt, creation and erosion of the boundary layer area.In the part, where the refractory is not in contact with the glass melt, the mechanism is characterized by a dissolution of alumina in refractory glass phase, diffusion of alkalis in glass phase from the refractory part below the glass level into the upper part, condensation and diffusion of evaporated volatile components of glass melt into the refractory material.


2015 ◽  
Vol 48 (7) ◽  
pp. 543-546
Author(s):  
O. Romanyuk ◽  
P. Jiricek ◽  
J. Zemek ◽  
J. Houdkova ◽  
K. Jurek ◽  
...  

Author(s):  
Ondrej Gedeon ◽  
Karel Jurek ◽  
Ivo Drbohlav ◽  
Nadège Ollier

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