Theoretical evaluation of high-energy lithium metal phosphate cathode materials in Li-ion batteries

2007 ◽  
Vol 165 (2) ◽  
pp. 887-891 ◽  
Author(s):  
Wilmont F. Howard ◽  
Robert M. Spotnitz
2018 ◽  
Vol 6 (7) ◽  
pp. 3134-3140 ◽  
Author(s):  
Ji Eon Kwon ◽  
Chang-Seok Hyun ◽  
Young Jun Ryu ◽  
Joungphil Lee ◽  
Dong Joo Min ◽  
...  

Triptycene bearing three benzoquinone moieties in a rigid 3-D tripod structure is capable of utilizing five-electron redox reactions that can provide a large capacity and high energy density in Li-ion cells.


2019 ◽  
Vol 43 (47) ◽  
pp. 18943-18950 ◽  
Author(s):  
Zhao Li ◽  
Qiang Li ◽  
Anbang Zhang ◽  
Wen Wen ◽  
Lin Wang ◽  
...  

Li- and Mn-rich (LMR) layered materials with large specific capacities are one of the most promising cathodes for high-energy Li-ion batteries.


Author(s):  
Narinthorn Wiriya ◽  
Yutthanakon Kanaphan ◽  
Rattiya Hongtong ◽  
Songyoot Kaewmala ◽  
Jeffrey Nash ◽  
...  

2015 ◽  
Vol 58 (11) ◽  
pp. 1809-1828 ◽  
Author(s):  
YiDi Zhang ◽  
Yi Li ◽  
XinHui Xia ◽  
XiuLi Wang ◽  
ChangDong Gu ◽  
...  

2014 ◽  
Vol 07 (04) ◽  
pp. 1430002 ◽  
Author(s):  
Liu Li ◽  
Kim Seng Lee ◽  
Li Lu

Li -rich layer-structured x Li 2 MnO 3 ⋅ (1 - x) LiMO 2 ( M = Mn , Ni , Co , etc.) materials have attracted much attention due to their extraordinarily high reversible capacity as the cathode material in Li -ion batteries. To better understand the nature of this type of materials, this paper reviews history of development of the Li -rich cathode materials, and provides in-depth study on complicated crystal structures and reaction mechanisms during electrochemical charge/discharge cycling. Despite the fabulous capability at low rate, several drawbacks still gap this type of high-capacity cathode materials from practical applications, for instance the large irreversible capacity loss at first cycle, poor rate capability, severe voltage decay and capacity fade during electrochemical charge/discharge cycling. This review will also address mechanisms for these inferior properties and propose various possible solutions to solve above issues for future utilization of these cathode materials in commercial Li -ion batteries.


2021 ◽  
Vol 9 ◽  
Author(s):  
Eunho Cha ◽  
Do Kyung Kim ◽  
Wonbong Choi

Often touted as the most promising next-generation energy storage systems, lithium (Li) metal batteries have drawn extensive interest due to their energy densities beyond those of Li-ion batteries. The use of Li metal, however, presents a major hurdle since it is susceptible to Li dendrite growths, corrosive interfacial reactions, and uncontrolled volume changes. Li-metal protection is an important issue in overcoming those challenges. In particular, studies have shown that molybdenum disulfide (MoS2) can significantly improve the performance and safety of Li metal batteries when used as a protective coating for anodes, separator modification, and stable interfacial layer between solid-electrolytes and Li metal. Herein, we review the successful implementation of MoS2 for improved Li metal batteries including those of the liquid-type and the solid-state cells. We also provide opportunities and prospects of MoS2 applications for safe and practical Li metal batteries.


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