Sulfonated poly(fluorenyl ether ketone nitrile) electrolyte membrane with high proton conductivity and low water uptake

2010 ◽  
Vol 195 (1) ◽  
pp. 97-103 ◽  
Author(s):  
S.H. Tian ◽  
D. Shu ◽  
S.J. Wang ◽  
M. Xiao ◽  
Y.Z. Meng
Keyword(s):  
Proton Conductivity ◽  
Water Uptake ◽  
High Proton Conductivity ◽  
Electrolyte Membrane ◽  
High Proton ◽  
Ether Ketone ◽  
Sulfonated Poly

Fully aromatic naphthalene-based sulfonated poly(arylene ether ketone)s with flexible sulfoalkyl groups as polymer electrolyte membranes

RSC Advances ◽  
2015 ◽  
Vol 5 (1) ◽  
pp. 536-544 ◽  
Author(s):  
Baolong Wang ◽  
Zhenzhen Cai ◽  
Na Zhang ◽  
Bin Zhang ◽  
Duo Qi ◽  
...  
Keyword(s):  
Thermal Stability ◽  
High Thermal Stability ◽  
Polymer Electrolyte Membranes ◽  
Methanol Permeability ◽  
High Proton Conductivity ◽  
Arylene Ether ◽  
High Proton ◽  
Electrolyte Membranes ◽  
Ether Ketone ◽  
Sulfonated Poly

Naphthalene-based poly(arylene ether ketone)s with pendant sulfoalkyl groups were prepared by a demethylation and sulfobutylation method. They exhibited high proton conductivity, low methanol permeability and high thermal stability.

scholarly journals Preparation and Characterization of Blending Sulfonated Poly(ether ether ketone) with Charged Surface Modifying Macromolecules

2017 ◽  
Vol 5 (1) ◽  
Author(s):  
M. N. A. Mohd–Norddin ◽  
A. F. Ismail ◽  
T. Matsuura ◽  
D. Rana
Keyword(s):  
Water Uptake ◽  
Mechanical Stability ◽  
Polymer Electrolyte Membrane ◽  
Blend Membrane ◽  
Electrolyte Membrane ◽  
Ether Ether Ketone ◽  
Poly Ether Ether Ketone ◽  
Ether Ketone ◽  
Speek Membrane ◽  
Sulfonated Poly

Charged surface modifying macromolecule (cSMM) end capped with sulfonic group was prepared and blended into sulfonated poly(ether ether ketone) (SPEEK). The modified membrane was characterized for polymer electrolyte membrane application; i.e. a SPEEK/cSMM blend membrane was compared to a SPEEK membrane and a Nafion 112 membrane for the thermal and mechanical stability, hydrophilicity and water uptake. Thermal and mechanical stability of the blend membrane were slightly reduced from that of the SPEEK membrane but still higher than that of the Nafion 112 membrane. The cSMM which was end–capped with sulfonic group has increased the total –SO3H group in the blend membrane. As a result, the blend membrane showed an increase in hydrophilicity and water uptake as compared to the pristine membrane. The addition of cSMM with an additional –SO3– charge has enabled the water uptake to be increased which is crucial to enhance the proton conductivity that of SPEEK. Moreover, the extra –SO3– can facilitate the transfer of proton better. This study found that cSMM is a good candidate as an additive for SPEEK in improving its function as polymer electrolyte membrane.

High proton conductivity of sulfonated methoxyphenyl-containing poly(arylene ether ketone) for proton exchange membranes

RSC Advances ◽  
2015 ◽  
Vol 5 (130) ◽  
pp. 107982-107991 ◽  
Author(s):  
Bo Dong ◽  
Yan Wang ◽  
Jinhui Pang ◽  
Shaowei Guan ◽  
Zhenhua Jiang
Keyword(s):  
Mechanical Properties ◽  
Proton Conductivity ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
High Proton Conductivity ◽  
Arylene Ether ◽  
High Proton ◽  
Ether Ketone ◽  
Polyelectrolyte Membrane

A polyelectrolyte membrane based on sulfonated methoxyphenyl-containing poly(arylene ether ketone) (SMP-PAEK) was obtained, which exhibited suitable proton conductivities and excellent mechanical properties.

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