A Sulfonated Polyimide/Nafion Blend Membrane with High Proton Selectivity and Remarkable Stability for Vanadium Redox Flow Battery

A sulfonated polyimide (SPI)/Nafion blend membrane composed of a designed and synthesized SPI polymer and the commercial Nafion polymer is prepared by a facile solution casting method for vanadium redox flow battery (VRFB). Similar molecular structures of both SPI and Nafion provide good compatibility and complementarity of the blend membrane. ATR-FTIR, 1H-NMR, AFM, and SEM are used to gain insights on the chemical structure and morphology of the blend membrane. Fortunately, the chemical stability of the SPI/Nafion blend membrane is effectively improved compared with reported SPI-based membranes for VRFB applications. In cycling charge-discharge tests, the VRFB with the as-prepared SPI/Nafion blend membrane shows excellent battery efficiencies and operational stability. Above results indicate that the SPI/Nafion blend membrane is a promising candidate for VRFB application. This work opens up a new possibility for fabricating high-performance SPI-based blend membrane by introduction of a polymer with a similar molecular structure and special functional groups into the SPI polymer.

Economic study for blend membrane production

Background In this work, an economic study for production reverse osmosis (RO) membrane from a blend of polyvinylchloride (PVC) with cellulose acetate (CA) was investigated. The model for predicting RO membrane performance was developed based on laboratory experimental data. The economic study was conducted to investigate the feasibility of producing blend RO polyvinylchloride/cellulose acetate (PVC/CA) membrane using a large-scale batch casting machine was developed and fabricated in workshop in the National Research Centre, Egypt. Results The cost of the prepared blend membrane using batch casting machine technique reached to 36 $/m2 for flat sheet polymeric membrane which was cheaper than the cost of sheets of commercial RO membranes. The original capital investment will be recovered in 7.5 years with estimation of machine lifetime 25 years. Conclusions The economic study revealed that the establishing small factories to produce blend membranes using the fabricated machine is a promising and will create a reasonable profit.

Mesoscale Morphologies of Nafion-Based Blend Membranes by Dissipative Particle Dynamics

Polymer electrolyte membrane (PEM) composed of polymer or polymer blend is a vital element in PEM fuel cell that allows proton transport and serves as a barrier between fuel and oxygen. Understanding the microscopic phase behavior in polymer blends is very crucial to design alternative cost-effective proton-conducting materials. In this study, the mesoscale morphologies of Nafion/poly(1-vinyl-1,2,4-triazole) (Nafion-PVTri) and Nafion/poly(vinyl phosphonic acid) (Nafion-PVPA) blend membranes were studied by dissipative particle dynamics (DPD) simulation technique. Simulation results indicate that both blend membranes can form a phase-separated microstructure due to the different hydrophobic and hydrophilic character of different polymer chains and different segments in the same polymer chain. There is a strong, attractive interaction between the phosphonic acid and sulfonic acid groups and a very strong repulsive interaction between the fluorinated and phosphonic acid groups in the Nafion-PVPA blend membrane. By increasing the PVPA content in the blend membrane, the PVPA clusters’ size gradually increases and forms a continuous phase. On the other hand, repulsive interaction between fluorinated and triazole units in the Nafion-PVTri blend is not very strong compared to the Nafion-PVPA blend, which results in different phase behavior in Nafion-PVTri blend membrane. This relatively lower repulsive interaction causes Nafion-PVTri blend membrane to have non-continuous phases regardless of the composition.