Solid state synthesis, structures and redox properties of the new [Mo6Bri7TeiBra6]3− and [Mo6Bri7SeiBra6]3− octahedral cluster units: Crystallochemistry of the Rb2+xMo6Bri8−xYixBra6 series (x=0.5 for Y=Te; 0.25⩽x⩽0.7 for Y=Se) and Rb2Mo6Br14

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