Synthesis, solution dynamics and chemical vapour deposition of heteroleptic zinc complexes via ethyl and amide zinc thioureides

Ethyl and amide zinc thioureides [L1ZnEt]2 (1), [L1*ZnEt]2 (2) and [L1Zn(N(SiMe3)2)]2 (3) have been synthesised from the equimolar reaction of thiourea ligands (HL1 = iPrN(H)CSNMe2 and HL1* = PhN(H)CSNMe2) with diethyl zinc and zinc...

A selective fluorescent probe for GadoliniumIII in water based on a PdII -preorganized chromone-receptor

The synthesis, solution studies, photochemical properties and the X-ray structure of a chromone based fluorescent PdII complex are reported. The ligand cointains two chromone units linked as side arms to...

Low Concentration Synthesis of Super-Amphiphilic Nanoflake ZSM-5 Film with Adjustable Property

High silica zeolite ZSM-5/glass film was successfully synthesized by an in-situ sol–gel dip-coating process combined with the steam-assisted conversion (SAC) technique with low concentration of the synthesis solution. The resulting zeolite films grown on the glass slide show amphiphilic properties. The growing process and the effect of the concentration of SiO2 in the silica source were examined. The mechanism of the formation of the nanoflake crystals and their wetting behavior was investigated. By simply adding fluorescein in the synthesis solution during the preparation, ZSM-5 films showing luminescence property can be obtained. Furthermore, these ZSM-5 zeolite films are easily modified to exhibit hydrophobic property.

Enhancing crystal quality and optical properties of GaN nanocrystals by tuning pH of the synthesis solution

Gallium nitride nanocrystals as a wide bandgap semiconductor material for optoelectronic applications can be synthesized using chemical methods. In this research using co-precipitation and nitridation processes gallium nitride nanocrystals have been synthesized, and by tuning pH of the synthesis solution at the co-precipitation step, crystal quality and optical property of the resultant gallium nitride nanocrystals have been enhanced. Gallium nitride nanocrystal samples were synthesized using solutions with pH values of 2.1, 4.8, 7.8, and 9.0, and then nitridation at 950 °C under the flow of ammonia gas. The synthesized nanocrystal samples were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and photoluminescence techniques. The XRD data show that the nanocrystals have hexagonal wurtzite crystal structure, and using Scherer’s equation the sizes of the synthesized nanocrystals are 23.6, 26.6, 19.7, and 10.4 nm for the samples synthesized using the solutions with pH values of 2.1, 4.8, 7.8, and 9.0 respectively. The sizes of the nanocrystals obtained from SEM images are larger than the values obtained using Scherer’s equation, due to the aggregation of nanocrystals. EDX spectra show that pH of the synthesis solution affects the elemental stoichiometry of the gallium nitride nanocrystals. We obtained better stoichiometry for the nanocrystal sample synthesized using solution with the pH of 4.8. Photoluminescence spectra show that for this sample the emission intensity is higher than the others.

Capacitance Enhancement by Incorporation of Functionalised Carbon Nanotubes into Poly(3,4-Ethylenedioxythiophene)/Graphene Oxide Composites

This paper reports on the role of oxidised carbon nanotubes (oxMWCNTs) present in poly-3,4-ethylenedioxytiophene (PEDOT)/graphene oxide (GOx) composite. The final ternary composites (pEDOT/GOx/oxMWCNTs) are synthesised by an electrodeposition process from the suspension-containing monomer, oxidised carbon nanotubes and graphene oxide. Dissociated functional groups on the surface of graphene oxide play a role of counter-ions for the polymer chains. Detailed physicochemical and electrochemical characterisation of the ternary composites is presented in the paper. The results prove that the presence of oxMWCNTs in the ternary composites doubles the capacitance values compared to the binary ones (450 vs. 270 F cm−3 for PEDOT/GOx/oxMWCNTs and PEDOT/GOx, respectively). The amount of carbon nanotubes in the synthesis solution is crucial for physicochemical properties of the composites, their adhesion to the electrode substrate and the electrochemical performance.

Image-Based Rendering of Cars using Semantic Labels and Approximate Reflection Flow

Image-Based Rendering (IBR) has made impressive progress towards highly realistic, interactive 3D navigation for many scenes, including cityscapes. However, cars are ubiquitous in such scenes; multi-view stereo reconstruction provides proxy geometry for IBR, but has difficulty with shiny car bodies, and leaves holes in place of reflective, semi-transparent windows on cars. We present a new approach allowing free-viewpoint IBR of cars based on an approximate analytic reflection flow computation on curved windows. Our method has three components: a refinement step of reconstructed car geometry guided by semantic labels, that provides an initial approximation for missing window surfaces and a smooth completed car hull; an efficient reflection flow computation using an ellipsoid approximation of the curved car windows that runs in real-time in a shader and a reflection/background layer synthesis solution. These components allow plausible rendering of reflective, semi-transparent windows in free viewpoint navigation. We show results on several scenes casually captured with a single consumer-level camera, demonstrating plausible car renderings with significant improvement in visual quality over previous methods.