Ball-milling synthesis of biochar and biochar–based nanocomposites and prospects for removal of emerging contaminants: A review

2021 ◽  
Vol 41 ◽  
pp. 101993
Author(s):  
Sefiu Olaitan Amusat ◽  
Temesgen Girma Kebede ◽  
Simiso Dube ◽  
Mathew Muzi Nindi
Keyword(s):  
Ball Milling ◽  
Emerging Contaminants

BALL MILLING OF INTERMETALLIC PHASES IN THE Nb-Al SYSTEM

1990 ◽  
Vol 51 (C4) ◽  
pp. C4-169-C4-174 ◽  
Author(s):  
M. OEHRING ◽  
R. BORMANN
Keyword(s):  
Ball Milling ◽  
Intermetallic Phases

High-energy ball milling

2010 ◽  
Author(s):  
Małgorzata Sopicka-Lizer
Keyword(s):  
Ball Milling ◽  
High Energy ◽  
High Energy Ball Milling ◽  
Energy Ball

Engineering Porosity Through Defects in a Giant Pore Metal–Organic Framework

2020 ◽  
Author(s):  
Adam Sapnik ◽  
Duncan Johnstone ◽  
Sean M. Collins ◽  
Giorgio Divitini ◽  
Alice Bumstead ◽  
...  
Keyword(s):  
Distribution Function ◽  
Ball Milling ◽  
Local Structure ◽  
Pair Distribution Function ◽  
Function Analysis ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Defect Engineering ◽  
Metal Organic ◽  
Unsaturated Metal Sites

<p>Defect engineering is a powerful tool that can be used to tailor the properties of metal–organic frameworks (MOFs). Here, we incorporate defects through ball milling to systematically vary the porosity of the giant pore MOF, MIL-100 (Fe). We show that milling leads to the breaking of metal–linker bonds, generating more coordinatively unsaturated metal sites, and ultimately causes amorphisation. Pair distribution function analysis shows the hierarchical local structure is partially</p><p>retained, even in the amorphised material. We find that the solvent toluene stabilises the MIL-100 (Fe) framework against collapse and leads to a substantial rentention of porosity over the non-stabilised material.</p>

Structure-controlled Nanomaterial Synthesis using Surfactant-assisted Ball Milling- A Review

2014 ◽  
Vol 10 (3) ◽  
pp. 344-354 ◽  
Author(s):  
Mahbub Ullah ◽  
Md. Ali ◽  
Sharifah Hamid
Keyword(s):  
Ball Milling ◽  
Nanomaterial Synthesis ◽  
Surfactant Assisted

scholarly journals Mechanochemical synthesis of poly(trimethylene carbonate)s: an example of rate acceleration

2019 ◽  
Vol 15 ◽  
pp. 963-970 ◽  
Author(s):  
Sora Park ◽  
Jeung Gon Kim
Keyword(s):  
Ball Milling ◽  
Mechanochemical Synthesis ◽  
Polymeric Materials ◽  
Solvent Free ◽  
Energy Output ◽  
Polymerization Temperature ◽  
Mechanical Degradation ◽  
Trimethylene Carbonate ◽  
Rate Acceleration ◽  
Conventional Solution

Mechanochemical polymerization is a rapidly growing area and a number of polymeric materials can now be obtained through green mechanochemical synthesis. In addition to the general merits of mechanochemistry, such as being solvent-free and resulting in high conversions, we herein explore rate acceleration under ball-milling conditions while the conventional solution-state synthesis suffer from low reactivity. The solvent-free mechanochemical polymerization of trimethylene carbonate using the organocatalysts 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) and 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) are examined herein. The polymerizations under ball-milling conditions exhibited significant rate enhancements compared to polymerizations in solution. A number of milling parameters were evaluated for the ball-milling polymerization. Temperature increases due to ball collisions and exothermic energy output did not affect the polymerization rate significantly and the initial mixing speed was important for chain-length control. Liquid-assisted grinding was applied for the synthesis of high molecular weight polymers, but it failed to protect the polymer chain from mechanical degradation.

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