Physical properties and electrochemical performance of LiNi0.5Mn1.5O4 cathode material prepared by a coprecipitation method

2007 ◽  
Vol 103 (1) ◽  
pp. 19-23 ◽  
Author(s):  
Yukai Fan ◽  
Jianming Wang ◽  
Xuebo Ye ◽  
Jianqing Zhang
2012 ◽  
Vol 27 (8) ◽  
pp. 838-842 ◽  
Author(s):  
Fei MOU ◽  
Xue-Lin YANG ◽  
Zhong-Xu DAI ◽  
Lu-Lu ZHANG ◽  
Zhao-Yin WEN

2011 ◽  
Vol 04 (03) ◽  
pp. 299-303 ◽  
Author(s):  
ZHUO TAN ◽  
PING GAO ◽  
FUQUAN CHENG ◽  
HONGJUN LUO ◽  
JITAO CHEN ◽  
...  

A multicomponent olivine cathode material, LiMn0.4Fe0.6PO4 , was synthesized via a novel coprecipitation method of the mixed transition metal oxalate. X-ray diffraction patterns indicate that carbon-coated LiMn0.4Fe0.6PO4 has been prepared successfully and that LiMn0.4Fe0.6PO4/C is crystallized in an orthorhombic structure without noticeable impurity. Homogeneous distribution of Mn and Fe in LiMn0.4Fe0.6PO4/C can be observed from the scanning electron microscopy (SEM) and the corresponding energy dispersive X-ray spectrometry (EDS) analysis. Hence, the electrochemical activity of each transition metal in the olivine synthesized via coprecipitation method was enhanced remarkably, as indicated by the galvanostatic charge/discharge measurement. The synthesized LiMn0.4Fe0.6PO4/C exhibits a high capacity of 158.6 ± 3 mAhg-1 at 0.1 C, delivering an excellent rate capability of 122.6 ± 3 mAhg-1 at 10 C and 114.9 ± 3 mAhg-1 at 20 C.


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