Two-dimensional lanthanide(III) cyclic coordination polymers complexes containing dimethyl phosphate ligand: Synthesis, spectroscopic characterization, thermal analysis, and crystal structures

2021 ◽  
Vol 1229 ◽  
pp. 129834
Author(s):  
Vahid Amani ◽  
Masoud Rafizadeh
Keyword(s):  
Thermal Analysis ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
Spectroscopic Characterization ◽  
Two Dimensional ◽  
Dimethyl Phosphate ◽  
Phosphate Ligand ◽  
Ligand Synthesis

One-dimensional and two-dimensional coordination polymers constructed from copper(II) nodes and polycarboxylato spacers: Synthesis, crystal structures and magnetic properties

Polyhedron ◽  
2008 ◽  
Vol 27 (2) ◽  
pp. 574-582 ◽  
Author(s):  
Cristian D. Ene ◽  
Floriana Tuna ◽  
Oscar Fabelo ◽  
Catalina Ruiz-Pérez ◽  
Augustin M. Madalan ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
Two Dimensional ◽  
One Dimensional

Two 2D Co(II)/Mn(II) coordination polymers based on the quinoline-2,3-dicarboxylate ligand: synthesis, crystal structure, and fluorescence properties

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Ya-Li Zhao ◽  
Qi-Ying Weng ◽  
Yu-Qian Xie ◽  
Jia-Ming Li
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Coordination Polymers ◽  
Fluorescence Properties ◽  
Stacking Interactions ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Solid State Fluorescence ◽  
2D Network

Abstract A pair of two-dimensional (2D) isostructural coordination polymers (CPs), {[Co(2,3-qldc)(H2O)]} n (1) and {[Mn(2,3-qldc)(H2O)]} n (2), where 2,3-H2qldc = quinoline-2,3-dicarboxylic acid, were hydrothermally synthesized and characterized through IR spectroscopy, elemental and thermal analysis, power X-ray diffraction, and single-crystal X-ray diffraction. The results have revealed that the fully deprotonated 2,3-H2qldc ligand connects the Co(II)/Mn(II) atoms with a μ 3-bridge to form a square-wave 2D network, which is further extended into 3D stacks through O–H···O, C–H···O hydrogen bonds and π···π stacking interactions. Topologically, 1 or 2 can be simplified as a 4-connected sql type with a Schläfli symbol {44·62} and a Shubnikov tetragonal plane net, or as a 3-connected fes type with a Schläfli symbol {4·82} and a Shubnikov plane net. The thermal stability and the solid state fluorescence properties of 1 and 2 were investigated.

Sign in / Sign up

Export Citation Format

Share Document