Thermodynamic properties of binary mixtures containing dimethyl carbonate+2-alkanol: Experimental data, correlation and prediction by ERAS model and cubic EOS

2013 ◽  
Vol 412 ◽  
pp. 100-105 ◽  
Author(s):  
Mohammad Almasi
Keyword(s):  
Experimental Data ◽  
Thermodynamic Properties ◽  
Binary Mixtures ◽  
Dimethyl Carbonate ◽  
Data Correlation ◽  
Eras Model

scholarly journals Prediction of excess molar volumes of binary mixtures by Prigogine-Flory-Patterson (PFP) and extended real association solution (ERAS) models

2017 ◽  
Vol 82 (12) ◽  
pp. 1379-1390 ◽  
Author(s):  
Ivona Radovic ◽  
Nikola Grozdanic ◽  
Bojan Djordjevic ◽  
Slobodan Serbanovic ◽  
Mirjana Kijevcanin
Keyword(s):  
Experimental Data ◽  
Theoretical Model ◽  
Binary Mixtures ◽  
Atmospheric Pressure ◽  
Binary Systems ◽  
Excess Molar Volumes ◽  
Molar Volumes ◽  
Eras Model ◽  
Data Points

In this paper, the Prigogine?Flory?Patterson (PFP) theoretical model and the extended real association solution (ERAS) model for the prediction of the excess molar volumes of 17 binary sets of alcohols (methanol, ethanol, propan-1-ol, butan-1-ol, butan-2-ol and pentan-1-ol) with benzene, chlorobenzene, acetonitrile, hexan-1-amine and n-heptane were tested at 298.15 K and atmospheric pressure. The binary sets contained 333 experimental data points for 11 different compounds. The ERAS model demonstrated better correlative characteristics for binary mixtures comparing to PFP model. The ERAS model is successfully applied on all binary systems except ethanol + benzene and propan-1-ol + benzene. PFP model gave less satisfactory results for all systems except butan-1-ol + hexan-1-amine, for which obtained results were acceptable.

scholarly journals Viscosities of binary mixtures of toluene with butan-1-ol and 2-methylpropan-2-ol

2005 ◽  
Vol 70 (11) ◽  
pp. 1313-1323 ◽  
Author(s):  
Vasile Dumitrescu ◽  
Octav Pântea
Keyword(s):  
Experimental Data ◽  
Thermodynamic Properties ◽  
Viscous Flow ◽  
Binary Mixtures ◽  
Liquid Mixtures ◽  
Viscosity Coefficients ◽  
Binary Liquid ◽  
Excess Viscosities ◽  
Flow Activation ◽  
Kister Equation

The viscosities of binary liquid mixtures of toluene with butan-1-ol and 2-methylpropan-2-ol have been determined at 298.15, 303.15, 308.15, 313.15 and 318.15 K over the whole concentration range. The Hind, Grunberg-Nissan, Wijk, Auslander and McAllister models were used to calculate the viscosity coefficients and these were compared with the experimental data for the mixtures. Excess viscosities were also calculated and fitted to the Redlich-Kister equation. Various thermodynamic properties of viscous flow activation were determined and their variations with composition are discussed.

Thermodynamic properties of binary mixtures containing thiaalkanes

1980 ◽  
Vol 77 ◽  
pp. 445-449 ◽  
Author(s):  
Zohra Ferhat-Hamida ◽  
Robert Philippe ◽  
Jean-Claude Merlin ◽  
V. Kehiaian
Keyword(s):  
Thermodynamic Properties ◽  
Binary Mixtures
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