Synthesis and structural characterization of a binary metal cluster and a coordination polymer based on the mercury Bis(phenylselenolate) unit

A new 1-D coordination polymer [M(CMe(O]2.5O (12.5O and the cluster [M((CPh (py(MeCN)(O)]2MeCN (22MeCN) are reported. Both compounds were synthesized by room temperature reactions of [M(-O)(CR(L()] (R = Me, L = = py, (12.5O; R = Ph, L = py, = O,22MeCN) in the presence of 3-hydroxymethylpyridine (3hmpH) in acetonitrile. The structures of these complexes are based on hexanuclear mixed-valent manganese carboxylate clusters containing the [(-O structural core. (12.5O consists of zigzag chain polymers constructed from [M(CMe(O] repeating units linked through acetate ligands, whereas22MeCN comprises a discrete M-benzoate cluster.

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Synthesis and structural characterization of Lindqvist type mixed-metal cluster anion [V2W4O19]4− in discrete and coordination polymer compounds

Journal of Molecular Structure ◽

10.1016/j.molstruc.2014.01.005 ◽

2014 ◽

Vol 1062 ◽

pp. 53-60 ◽

Cited By ~ 6

Author(s):

Sridevi Yerra ◽

Srinivasa Rao Amanchi ◽

Samar K. Das

Keyword(s):

Coordination Polymer ◽

Structural Characterization ◽

Metal Cluster ◽

Cluster Anion ◽

Mixed Metal ◽

Mixed Metal Cluster

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Coordination of Polythioether Macrocycles to Metal Cluster Complexes. 1. The Synthesis and Structural Characterization of Ru5(CO)13(.mu.-.eta.1-12S3)(.mu.5-C) and Ru5(CO)11(.mu.-.eta.3-12S3)(.mu.5-C), 12S3 = 1,5,9-Trithiacyclododecane

Organometallics ◽

10.1021/om00024a032 ◽

1994 ◽

Vol 13 (12) ◽

pp. 4870-4874 ◽

Cited By ~ 5

Author(s):

Richard D. Adams ◽

Stephen B. Falloon ◽

Kenneth T. McBride

Keyword(s):

Structural Characterization ◽

Metal Cluster ◽

Cluster Complexes

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Synthesis and Structural Characterization of a Cobalt Coordination Polymer with Bis(4-(1H-imidazol-1-yl)phenyl)methanone and 4-Nitrophthalate

Crystallography Reports ◽

10.1134/s106377451807026x ◽

2018 ◽

Vol 63 (7) ◽

pp. 1124-1128 ◽

Cited By ~ 1

Author(s):

G.-F. Wang ◽

S.-W. Sun

Keyword(s):

Coordination Polymer ◽

Structural Characterization ◽

Cobalt Coordination

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ChemInform Abstract: SYNTHESIS AND REACTIONS OF BINARY METAL SULFIDES. STRUCTURAL CHARACTERIZATION OF THE ((S4)2ZN)2-, ((S4)2NI)2-, ((S5)MN(S6))2-, AND ((CS4)2NI)2- ANIONS

Chemischer Informationsdienst ◽

10.1002/chin.198525317 ◽

1985 ◽

Vol 16 (25) ◽

Author(s):

D. COUCOUVANIS ◽

P. R. PATIL ◽

M. G. KANATZIDIS ◽

B. DETERING ◽

N. C. BAENZIGER

Keyword(s):

Structural Characterization ◽

Metal Sulfides ◽

Binary Metal

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Synthesis and structural characterization of a single-crystal to single-crystal transformable coordination polymer

Dalton Transactions ◽

10.1039/c3dt52579a ◽

2014 ◽

Vol 43 (4) ◽

pp. 1519-1523 ◽

Cited By ~ 14

Author(s):

Yuyang Tian ◽

Phoebe K. Allan ◽

Catherine L. Renouf ◽

Xiang He ◽

Laura J. McCormick ◽

...

Keyword(s):

Coordination Polymer ◽

Single Crystal ◽

Structural Characterization

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Synthesis and structural characterization of transition metal dithiolene derivatives containing divalent metals as counter-cations

CrystEngComm ◽

10.1039/c8ce01916a ◽

2019 ◽

Vol 21 (9) ◽

pp. 1423-1432 ◽

Cited By ~ 1

Author(s):

Oscar Castillo ◽

Esther Delgado ◽

Diego Hernández ◽

Elisa Hernández ◽

Avelino Martín ◽

...

Keyword(s):

Coordination Polymer ◽

Transition Metal ◽

Structural Characterization ◽

Metal Cations ◽

Magnetic Behaviour ◽

Divalent Metal ◽

Divalent Metals ◽

Divalent Metal Cations ◽

1D Coordination Polymer

Complexes containing [Fe2(SC6H2Cl2S)4]2− or [Ni(SC6H2Cl2S)2]− entities and divalent metal cations as well as an 1D-coordination polymer K/Zn have been obtained and their magnetic behaviour studied.

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