Hydrophobic, moisture resistant and biorenewable paper coating derived from castor oil based epoxy methyl ricinoleate with repulpable potential

Realizing abundant availability of local bovine bone wastes in Aceh Province, Indonesia, this study is subjected to take competitive advantages from the local bovine bone waste for preparing an inorganic catalyst preparation. In detail, calcined Aceh bovine bones were successfully intercalated lithium through an impregnation method resulting in the inorganic base catalyst, which showed promising activity in the transesterification of castor oil. Prior to the experiment, the Aceh bovine bone waste was calcined at 900 oC in the air atmosphere for 4 hours, led to forming crystalline phases of hydroxyapatite [Ca5(PO4)3(OH)] and calcium oxide [CaO]. Also, the chemical modification of calcined bovine bone with lithium precursor has enhanced the physicochemical properties of the inorganic base catalyst. Finally, the intercalated Aceh bovine bone has shown a feasible activity in transesterification of castor oil into biodiesel, which yielding methyl ricinoleate as the main product.

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Sulfosuccination of Methyl Ricinoleate and Methyl 12-Hydroxy Stearate Derived from Renewable Castor Oil and Evaluation of Their Surface Properties

Journal of Surfactants and Detergents ◽

10.1007/s11743-016-1804-0 ◽

2016 ◽

Vol 19 (3) ◽

pp. 447-454 ◽

Cited By ~ 1

Author(s):

Pandari Phani Kumar ◽

Peketi Ramesh ◽

Sanjit Kanjilal

Keyword(s):

Surface Properties ◽

Castor Oil ◽

Methyl Ricinoleate

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Renewable Approach To Synthesize Highly Toughened Bioepoxy from Castor Oil Derivative–Epoxy Methyl Ricinoleate and Cured with Biorenewable Phenalkamine

Industrial & Engineering Chemistry Research ◽

10.1021/acs.iecr.8b02043 ◽

2018 ◽

Vol 57 (33) ◽

pp. 11323-11334 ◽

Cited By ~ 10

Author(s):

Sushanta K. Sahoo ◽

Vinay Khandelwal ◽

Gaurav Manik

Keyword(s):

Castor Oil ◽

Methyl Ricinoleate

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Chemical modifications of ricinolein in castor oil and methyl ricinoleate for viscosity reduction to facilitate their use as biodiesels

European Journal of Lipid Science and Technology ◽

10.1002/ejlt.201500120 ◽

2015 ◽

Vol 118 (4) ◽

pp. 651-657 ◽

Cited By ~ 6

Author(s):

Sai Ba ◽

Hao Zhang ◽

Yiqin Jasmine Lee ◽

Chee Wee Ng ◽

Tianhu Li

Keyword(s):

Castor Oil ◽

Methyl Ricinoleate ◽

Viscosity Reduction ◽

Chemical Modifications

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Diazole and triazole derivatives of castor oil extract: synthesis, hypoglycemic effect, antioxidant potential and antimicrobial activity

Grasas y Aceites ◽

10.3989/gya.0342191 ◽

2020 ◽

Vol 71 (4) ◽

pp. 378

Author(s):

F. Taieb Brahimi ◽

F. Belkhadem ◽

B. Trari ◽

A. A. Othman

Keyword(s):

Castor Oil ◽

Amylase Activity ◽

Antioxidant Properties ◽

Methyl Ricinoleate ◽

Oil Seeds ◽

Triazole Derivatives ◽

Antifungal Effects ◽

Oil Extract ◽

Antibacterial And Antifungal ◽

Derivatives Of

The ricinoleate triglyceride was extracted from castor-oil seeds grown in Algeria and isolated by catalytically methanolyse to methyl ricinoleate. Six diazole and triazole derivatives of ricinoleic acid were synthesized and characterized: 1,3,4-oxadiazole-5-thione (4); 1,3,4-thiadiazole-5-thione (5); 4-N-amino-1,2,4-triazole-5-thiol (7); 1,2,4-triazole-5-thione (9); 5-amino-1,3,4-oxadiazole (10) and 5-amino-1,3,4-thiadiazole (11). The antibacterial and antifungal screening data of synthesized compounds showed appreciable inhibition and among them, 5, 7 and 8 showed more inhibition on Gram positive Enterococcus faecalis than reference ampiciline; while compounds 1, 7, 8, 10 and 11 showed competitive antifungal effects compared to reference amphotericin B. In addition, all synthesized compounds (1-11) showed competitive antioxidant properties, particularly compounds 7 at 125, 250, 500 and 1000 μg/mL and compounds 4, 5 and 9 at a concentration of 1000 μg/mL. The intermediate compounds 1, 2 and 8 showed anti-α-amylase activity at various concentrations in the range of IC50 = (120.25 ± 1.17 - 130.42 ± 2.48). Oxadiazole 4 showed the best α-amylase inhibition by 78.5% at a concentration of 1000 μg/mL.

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