1H and 13C NMR spectra, structure and physicochemical features of phenyl acridine-9-carboxylates and 10-methyl-9-(phenoxycarbonyl)acridinium trifluoromethanesulphonates – alkyl substituted in the phenyl fragment

Author(s):  
K. Krzymiński ◽  
P. Malecha ◽  
B. Zadykowicz ◽  
A. Wróblewska ◽  
J. Błażejowski
2018 ◽  
Vol 69 (1) ◽  
pp. 64-69
Author(s):  
Liviu Birzan ◽  
Mihaela Cristea ◽  
Constantin C. Draghici ◽  
Alexandru C. Razus

The 1H and 13C NMR spectra of several 2,6-diheteroarylvinyl heterocycles containing 4-azulenyl moiety were recorded and their proton and carbon chemical shifts were compared with those of the compounds without double bond between the heterocycles. The influence of the nature of central and side heterocycles, molecule polarization and anisotropic effects were revealed. The highest chemical shifts were recorded for the pyrylium salts and the lowest at pyridines, but in the case of the pyridinium salts, the protons chemical shifts at the central heterocycle are more shielded due to a peculiar anisotropy of the attached vinyl groups.


1994 ◽  
Vol 262 (2) ◽  
pp. 173-184 ◽  
Author(s):  
Tadasu Urashima ◽  
William A. Bubb ◽  
Michael Messer ◽  
Yuhnagi Tsuji ◽  
Yasuko Taneda

ChemInform ◽  
2010 ◽  
Vol 27 (50) ◽  
pp. no-no
Author(s):  
N. E. ALEXANDROU ◽  
G. E. MERTZANOS ◽  
J. STEPHANIDOU-STEPHANATOU ◽  
C. A. TSOLERIDIS

2020 ◽  
Vol 15 (10) ◽  
pp. 1934578X2093378
Author(s):  
Josep Coll Toledano

The present review of NMR spectroscopic structural elucidation data of new compounds isolated from Scutellaria species is focused on the title compounds, displaying a peculiar 13-spiro feature. It contains a compilation of 1H and 13C NMR data of these diterpenoids grouped by similar substitution patterns. Comparing shielding effects pointed out not only the identity of some compounds (already reported) but also potential misassignments and convenient revisions to get unambiguous structural proposals.


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