Growth and characterization of Pb(Mg1/3Nb2/3)O3–PbTiO3–PbZrO3 single crystals with high rhombohedral/tetragonal phase transition temperature

2008 ◽  
Vol 145 (1-2) ◽  
pp. 38-42 ◽  
Author(s):  
Zhiguo Xia ◽  
Qiang Li ◽  
Shaofeng Zhang
2011 ◽  
Vol 105 (1) ◽  
pp. 103-109 ◽  
Author(s):  
Tina Nestler ◽  
Kay Potzger ◽  
Hartmut Stöcker ◽  
Barbara Abendroth ◽  
Ralph Strohmeyer ◽  
...  

2020 ◽  
Vol 49 (34) ◽  
pp. 11931-11941
Author(s):  
Eiki Niwa ◽  
Tsubasa Sato ◽  
Takuya Hashimoto

The standard entropy change, ΔS°, and enthalpy change, ΔH°, at the structural phase transition of Pr2−xNdxNiO4+δ and their impact on variation of phase transition temperature by Nd content.


2014 ◽  
Vol 04 (01) ◽  
pp. 1450002
Author(s):  
Guisheng Xu ◽  
Danfeng Yang ◽  
Jinfeng Liu ◽  
Ying Liu ◽  
Xiaxia Chen

Our progress in the growth of ternary system Pb ( In 1/2 Nb 1/2) O 3– Pb ( Mg 1/3 Nb 2/3) O 3– PbTiO 3 (PIMNT) crystals and reviews on the possible developing trends in the piezoelectric crystals are presented. Large PIMNT crystals with 3 inches in diameter have been grown by using a modified Bridgman method. Meanwhile, Mn -doped PIMNT crystals have also been obtained. PIMNT crystals exhibit Curie temperature Tc ~ 190° C , rhombohedral–tetragonal phase transition temperature T rt > 100° C and coercive field Ec ~ 5.0–7.0 kV/cm on (001) cuts. Meanwhile, higher piezoelectric constant d32 ~ -1500–2200 pC/N , d15 ~ 4000–6000 pC/N and coercive field Ec ~ 7.0–9.0 kV/cm have been achieved on (110) cuts. The development trends of relaxor-based ferroelectric crystals are suggested to grow novel crystals with high rhombohedral–tetragonal phase transition temperature T rt > 150 ~ 160° C and/or high coercive field Ec and mechanical quality factor Qm, to promote growth efficiency of PIMNT crystals and to create new growth methods fitting for the growth of metastable or instable crystals.


2010 ◽  
Vol 96 (7) ◽  
pp. 071901 ◽  
Author(s):  
R. Loetzsch ◽  
A. Lübcke ◽  
I. Uschmann ◽  
E. Förster ◽  
V. Große ◽  
...  

Open Physics ◽  
2013 ◽  
Vol 11 (1) ◽  
Author(s):  
Ae Lim ◽  
Se-Young Jeong

AbstractDeuterium resonance investigations of KD3(SeO3)2 single crystals have been performed near the phase transition temperature T C. There are two types of deuterium bonds in these crystals with different behaviors at this phase transition. Our experimental results show that there are significant changes in the D spinlattice relaxation time T 1 at T C; the abrupt decrease in T 1 near T C can be explained by the critical slowing down of an overdamped soft pseudospin-type deuteron mode. Further, the ordering of the O(2)…D… O(2) bonds is affected by the phase transition, whereas the ordering of the O(1)-D… O(3) bonds is unaffected. The D NMR measurements also show that the D(2) deuteron disordering above T C is dynamic and not static.


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