Efficient synthesis of 1,2,4-oxadiazine-5-ones via [3+3] cycloaddition of in situ generated aza-oxyallylic cations with nitrile oxides

2018 ◽  
Vol 59 (21) ◽  
pp. 2018-2020 ◽  
Author(s):  
Gangqiang Wang ◽  
Rongxing Chen ◽  
Sen Zhao ◽  
Liangfeng Yang ◽  
Haibing Guo ◽  
...  
Keyword(s):  
Efficient Synthesis ◽  
Nitrile Oxides

Asymmetric 1,3-Dipolar Cycloaddition of Nitrile Oxides Generated in situ by Direct Oxidation of Aldoximes

2002 ◽  
Vol 31 (11) ◽  
pp. 1112-1113 ◽  
Author(s):  
Masamichi Tsuji ◽  
Yutaka Ukaji ◽  
Katsuhiko Inomata
Keyword(s):  
Dipolar Cycloaddition ◽  
Direct Oxidation ◽  
Nitrile Oxides

scholarly journals Indium-Catalyzed Direct Conversion of Lactones into Thiolactones Using a Disilathiane as a Sulfur Source

2018 ◽  
Author(s):  
Yohei Ogiwara ◽  
Ken Takano ◽  
Shuhei Horikawa ◽  
Norio Sakai
Keyword(s):  
Elemental Sulfur ◽  
Direct Conversion ◽  
Pharmaceutical Chemistry ◽  
Sulfur Source ◽  
Efficient Synthesis ◽  
Previous Reaction ◽  
Indium Catalyst

Indium-catalyzed reaction of lactones and a disilathiane leading to thiolactones is described. The direct synthesis of thiolactones from lactones with an appropriate sulfur source is one of the most attractive approaches in organic and pharmaceutical chemistry. In this context, we found an indium-catalyzed direct conversion of lactones into thiolactones in the presence of elemental sulfur and a hydrosilane via formation of the disilathiane in-situ. On the basis of the previous reaction, the application utilizing the disilathiane as a sulfur source was performed herein for the efficient synthesis of a variety of thiolactone derivatives from lactones by an indium-catalyst.

Efficient Synthesis of Diospyrol via Suzuki-Miyaura and Modified in situ Cross-Coupling

Synthesis ◽  
2005 ◽  
Vol 2005 (17) ◽  
pp. 2934-2938
Author(s):  
Somsak Ruchirawat ◽  
Poolsak Sahakitpichan ◽  
Nopporn Thasana
Keyword(s):  
Cross Coupling ◽  
Efficient Synthesis

scholarly journals Efficient synthesis of ponasterone A by recombinant Escherichia coli harboring the glycosyltransferase GTBP1with in situ product removal

RSC Advances ◽  
2017 ◽  
Vol 7 (37) ◽  
pp. 23027-23029 ◽  
Author(s):  
Bingfeng Li ◽  
Xuejun He ◽  
Bo Fan ◽  
Jianlin Chu ◽  
Bingfang He
Keyword(s):  
Escherichia Coli ◽  
Bacillus Pumilus ◽  
Recombinant Escherichia Coli ◽  
Efficient Synthesis ◽  
In Situ Product Removal ◽  
Product Removal ◽  
Ponasterone A

A glycosyltransferase GTBP1fromBacillus pumilusBF1 was isolated.

A New Route to Nitrile Oxides from Primary Alkylhalides for in situ Dipolar Cycloadditions

Synlett ◽  
1998 ◽  
Vol 1998 (4) ◽  
pp. 385-386 ◽  
Author(s):  
Dilipkumar Maiti ◽  
Pranab K. Bhattacharya
Keyword(s):  
Dipolar Cycloadditions ◽  
Nitrile Oxides
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