Effects of dissolved oxygen on formation of corrosion products and concomitant oxygen and nitrate reduction in zero-valent iron systems with or without aqueous Fe2+

2005 ◽  
Vol 39 (9) ◽  
pp. 1751-1760 ◽  
Author(s):  
Yong H. Huang ◽  
Tian C. Zhang
Keyword(s):  
Dissolved Oxygen ◽  
Nitrate Reduction ◽  
Corrosion Products ◽  
Zero Valent Iron

Nitrate reduction over nanoscale zero-valent iron prepared by hydrogen reduction of goethite

2012 ◽  
Vol 133 (1) ◽  
pp. 205-211 ◽  
Author(s):  
H.B. Liu ◽  
T.H. Chen ◽  
D.Y. Chang ◽  
D. Chen ◽  
Y. Liu ◽  
...  
Keyword(s):  
Nitrate Reduction ◽  
Hydrogen Reduction ◽  
Zero Valent Iron ◽  
Nanoscale Zero Valent Iron

Common oxidants activate the reactivity of zero-valent iron (ZVI) and hence remarkably enhance nitrate reduction from water

2015 ◽  
Vol 146 ◽  
pp. 227-234 ◽  
Author(s):  
Xuejun Guo ◽  
Zhe Yang ◽  
Hong Liu ◽  
Xiaofang Lv ◽  
Qiansi Tu ◽  
...  
Keyword(s):  
Nitrate Reduction ◽  
Zero Valent Iron

Dissolved oxygen and nitrate effects on the reduction and removal of divalent mercury by pumice supported nanoscale zero-valent iron

2018 ◽  
Vol 4 (10) ◽  
pp. 1651-1661 ◽  
Author(s):  
Ghulam Hussain Qasim ◽  
Sangwook Lee ◽  
Giehyeon Lee ◽  
Woojin Lee ◽  
Yongseok Hong ◽  
...  
Keyword(s):  
Dissolved Oxygen ◽  
Zero Valent Iron ◽  
Nanoscale Zero Valent Iron

Absence of dissolved oxygen and presence of nitrate in groundwater increases Hg(0) during the Hg(ii) removal using pumice supported nZVI.

Evaluation of nanoscale zero valent iron filled column for nitrate reduction

2018 ◽  
Vol 32 (3) ◽  
pp. 243-251 ◽  
Author(s):  
Youngpyoe Hong ◽  
Younggyo Seo ◽  
Hyowon Kim ◽  
Yuhoon Hwang
Keyword(s):  
Nitrate Reduction ◽  
Zero Valent Iron ◽  
Nanoscale Zero Valent Iron

scholarly journals Chemical Reduction of Nitrate by Zero-Valent Iron: Shrinking-Core versus Surface Kinetics Models

2020 ◽  
Vol 17 (4) ◽  
pp. 1241 ◽  
Author(s):  
Maria Villen-Guzman ◽  
Juan Manuel Paz-Garcia ◽  
Brahim Arhoun ◽  
Maria del Mar Cerrillo-Gonzalez ◽  
Jose Miguel Rodriguez-Maroto ◽  
...  
Keyword(s):  
Nitrate Reduction ◽  
Chemical Reduction ◽  
Permeable Reactive Barriers ◽  
Zero Valent Iron ◽  
Sound Design ◽  
Surface Kinetics ◽  
Ph Values ◽  
Stirred Reactor ◽  
Constant Ph ◽  
Shrinking Core

Zero valent iron (ZVI) is being used in permeable reactive barriers (PRB) for the removal of oxidant contaminants, from nitrate to chlorinated organics. A sound design of these barriers requires a good understanding of kinetics. Here we present a study of the kinetics of nitrate reduction under relatively low values of pH, from 2 to 4.5. We use a particle size of 0.42 mm, which is within the recommended size for PRBs (0.2 mm to 2.0 mm). In order to avoid possible mass-transfer limitations, a well-stirred reactor coupled with a fluidized bed reactor was used. The experiments were performed at constant pH values using a pH controller that allows to accurately track the amount of acid added. Since the reduction of H + to H 2 by the oxidation of ZVI will always be present for these pH values, blank experiments (without nitrate) were performed and the rate of this H + reduction obtained. This rate of reduction was studied using three kinetic models: a regular empirical one, the Shrinking-Core Model (SCM), and the Surface Kinetics Model (SKM). The best performance was obtained from the SKM model. Therefore, this model was also used to study the results for the nitrate reduction, also with satisfactory results. In both cases, some assumptions are introduced to maintain a moderate number of fitting parameters.

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