Photo-induced ligand exchange reactions of ferrocenylacetylacetone in the presence of pyridine or 4,4′-dipyridyl: Crystal and molecular structure of trans-bis(ferrocenylacetylacetonato)dipyridineiron(II), [Fe(FAnato)2(Py)2]

1998 ◽  
Vol 568 (1-2) ◽  
pp. 165-169 ◽  
Author(s):  
De-Ji Che ◽  
Gang Li ◽  
Xiao Lan Yao ◽  
Da Peng Zou
Keyword(s):  
Molecular Structure ◽  
Ligand Exchange ◽  
Crystal And Molecular Structure ◽  
Exchange Reactions

scholarly journals Tris(phosphan)-Nickel(0)-Ethen-Komplexe (dmpe)(PR3)Ni(C2H4). Molekülstruktur des (dmpe)(PØ3 )Ni(C2H4)/ Tris(phosphane)-nickel(0)-ethene Complexes (dmpe)(PR3)Ni(C2H4). Molecular Structure of (dmpe)(PO3)Ni(C2H4)

1984 ◽  
Vol 39 (8) ◽  
pp. 1076-1081 ◽  
Author(s):  
Klaus R. Pörschke ◽  
Richard Mynott ◽  
Carl Krüger ◽  
M. J. Romão
Keyword(s):  
Molecular Structure ◽  
Ligand Exchange ◽  
Crystal And Molecular Structure ◽  
Exchange Reactions ◽  
Tetrahedral Geometry ◽  
X Ray ◽  
X Ray Crystallography ◽  
Nmr Data

AbstractSynthesis and properties of tris(phosphane)(ethene)nickel(0) complexes (dmpe)(PR3)Ni(C2H4) (R = CH3(4), c-C6H11(5), and C6H5 (6)) are reported. In solution. 4-6 are thermolabile and undergo ligand exchange reactions affording tetrakis(phosphane)nickel(0 ) and bis(phosphane)- (ethene)nickel(0) complexes. 1H, 13C, and 31P NMR data of 4-6 confirm the tetrahedral geometry around nickel. For 6 , the crystal and molecular structure has been determined by X-ray crystallography.

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