ChemInform Abstract: CRYSTAL AND MOLECULAR STRUCTURE AND THE KINETICS OF LIGAND EXCHANGE OF TRIS(N,N-DIMETHYLDITHIOCARBAMATO)THALLIUM(III)

1975 ◽  
Vol 6 (46) ◽  
Author(s):  
H. ABRAHAMSON ◽  
J. R. HEIMAN ◽  
L. H. PIGNOLET
1984 ◽  
Vol 39 (8) ◽  
pp. 1076-1081 ◽  
Author(s):  
Klaus R. Pörschke ◽  
Richard Mynott ◽  
Carl Krüger ◽  
M. J. Romão

AbstractSynthesis and properties of tris(phosphane)(ethene)nickel(0) complexes (dmpe)(PR3)Ni(C2H4) (R = CH3(4), c-C6H11(5), and C6H5 (6)) are reported. In solution. 4-6 are thermolabile and undergo ligand exchange reactions affording tetrakis(phosphane)nickel(0 ) and bis(phosphane)- (ethene)nickel(0) complexes. 1H, 13C, and 31P NMR data of 4-6 confirm the tetrahedral geometry around nickel. For 6 , the crystal and molecular structure has been determined by X-ray crystallography.


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