Tris(phosphan)-Nickel(0)-Ethen-Komplexe (dmpe)(PR3)Ni(C2H4). Molekülstruktur des (dmpe)(PØ3 )Ni(C2H4)/ Tris(phosphane)-nickel(0)-ethene Complexes (dmpe)(PR3)Ni(C2H4). Molecular Structure of (dmpe)(PO3)Ni(C2H4)
1984 ◽
Vol 39
(8)
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pp. 1076-1081
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Keyword(s):
X Ray
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AbstractSynthesis and properties of tris(phosphane)(ethene)nickel(0) complexes (dmpe)(PR3)Ni(C2H4) (R = CH3(4), c-C6H11(5), and C6H5 (6)) are reported. In solution. 4-6 are thermolabile and undergo ligand exchange reactions affording tetrakis(phosphane)nickel(0 ) and bis(phosphane)- (ethene)nickel(0) complexes. 1H, 13C, and 31P NMR data of 4-6 confirm the tetrahedral geometry around nickel. For 6 , the crystal and molecular structure has been determined by X-ray crystallography.
1994 ◽
Vol 49
(4)
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pp. 441-444
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1986 ◽
Vol 41
(10)
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pp. 1211-1218
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1998 ◽
Vol 568
(1-2)
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pp. 165-169
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Keyword(s):
1995 ◽
Vol 50
(1)
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pp. 139-146
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