A two-dimensional molybdenum (V) phosphate with covalently bonded transition metal coordination complexes: hydrothermal synthesis and structure characterization of Na2[{Mn(phen)2(H2O)}{Mn(phen)2}3{Mn Mo12vO24 (HPO4)6(PO4)2(OH)6}]·4H2O (phen=1, 10-phenanthroline)

2003 ◽  
Vol 170 (1) ◽  
pp. 192-197 ◽  
Author(s):  
Mei Yuan ◽  
Enbo Wang ◽  
Ying Lu ◽  
Yangguang Li ◽  
Changwen Hu ◽  
...  
2006 ◽  
Vol 800 (1-3) ◽  
pp. 69-73 ◽  
Author(s):  
Jie-Hui Yu ◽  
Qin Hou ◽  
Ming-Hui Bi ◽  
Zheng-Liang Lü ◽  
Xiao Zhang ◽  
...  

2015 ◽  
Vol 1088 ◽  
pp. 309-313
Author(s):  
Chang Feng Sun ◽  
Yan Yan Pang ◽  
Ying Zhao ◽  
Yu Yang

Under hydrothermal conditions, two copper phosphonates, [Cu2(H2O)2(H2L)(bpy)2(H3L)2]·2H2O (1) and [Cu2(H2O)2(H2L)2(phen)2]·6H2O (2) (H4L = p-xylylenediphosphonic acid, bpy = 2,2'-bipyridine and phen = 1,10-phenanthroline), have been synthesized using diethyl p-xylylenediphosphonate (dixdp), in which p-xylylenediphosphonic acid (H4L) was generated via in situ hydrolysis. Complexe 1 forms a zero-dimensional (0D) bimetallic rings, while complex 2 features a 0D structure containing two kinds of partially deprotonated H3L-and H2L2-ligand.


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