Transannular vs Intramolecular Insertion Reactions of Transition Metal Carbenes: Evaluation of a Transannular Approach to Cyclooctane Ring Synthesis

Tetrahedron ◽  
2000 ◽  
Vol 56 (49) ◽  
pp. 9555-9567 ◽  
Author(s):  
James D. Dudones ◽  
Paul Sampson
Keyword(s):  
Transition Metal ◽  
Insertion Reactions ◽  
Metal Carbenes ◽  
Ring Synthesis

Chiral proton-transfer shuttle catalysts for carbene insertion reactions

2018 ◽  
Vol 16 (17) ◽  
pp. 3087-3094 ◽  
Author(s):  
Yuan-Yuan Ren ◽  
Shou-Fei Zhu ◽  
Qi-Lin Zhou
Keyword(s):  
Transition Metal ◽  
Proton Transfer ◽  
Insertion Reactions ◽  
Carbene Insertion ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

The development of chiral proton-transfer shuttles provides a totally new enantiocontrol strategy for transition metal-catalyzed asymmetric carbene insertion reactions.

A New Route to Coordination Complexes of Nitroxyl (HNO) via Insertion Reactions of Nitrosonium Triflate with Transition-Metal Hydrides

2002 ◽  
Vol 124 (41) ◽  
pp. 12068-12069 ◽  
Author(s):  
Rory Melenkivitz ◽  
Joel S. Southern ◽  
Gregory L. Hillhouse ◽  
Thomas E. Concolino ◽  
Louise M. Liable-Sands ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Coordination Complexes ◽  
Insertion Reactions ◽  
Transition Metal Hydrides
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