β-Carbonyl radicals as three-carbon building blocks for carbon-carbon bond forming reactions

Tetrahedron ◽  
1985 ◽  
Vol 41 (19) ◽  
pp. 4025-4037 ◽  
Author(s):  
Bernd Giese ◽  
Hans Horler
Keyword(s):  
Building Blocks ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions

Recent Advances in the Carbon–Carbon Bond-Forming Reactions of N-Acylketimines

Synthesis ◽  
2017 ◽  
Vol 49 (15) ◽  
pp. 3366-3376 ◽  
Author(s):  
Haruyasu Asahara
Keyword(s):  
Nucleophilic Addition ◽  
Building Blocks ◽  
Carbon Bond ◽  
Type Reaction ◽  
Carbon Centers ◽  
Bond Forming ◽  
Amino Compounds ◽  
Carbon Carbon Bond ◽  
Amide Derivatives ◽  
Bond Forming Reactions

N-Acylketimines are important synthetic building blocks used in the synthesis of a wide variety of functional amino compounds including cyclic and acyclic products. This review focuses on carbon–carbon bond-forming reactions of N-acylketimines to construct amino compounds having tetrasubstituted carbon centers.1 Introduction2 Preparation of N-Acylketimines2.1 Nucleophilic Addition of Amide Derivatives2.2 Acylation of Imine Derivatives2.3 An Aza-Wittig-Type Reaction2.4 Oxidation of Amine Precursors3 Reactions of N-Acylketimines3.1 Cyclic Ketimines3.2 Acyclic Ketimines4 Conclusions

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