The first example of chiral induction using homochiral boronic esters in the Petasis reaction

2002 ◽  
Vol 43 (34) ◽  
pp. 5969-5970 ◽  
Author(s):  
Tobias Koolmeister ◽  
Mikael Södergren ◽  
Martin Scobie
Keyword(s):  
Chiral Induction ◽  
Petasis Reaction ◽  
Boronic Esters

ChemInform Abstract: The First Example of Chiral Induction Using Homochiral Boronic Esters in the Petasis Reaction.

ChemInform ◽  
2010 ◽  
Vol 33 (45) ◽  
pp. no-no
Author(s):  
Tobias Koolmeister ◽  
Mikael Soedergren ◽  
Martin Scobie
Keyword(s):  
Chiral Induction ◽  
Petasis Reaction ◽  
Boronic Esters

ChemInform Abstract: Pinacolyl Boronic Esters as Components in the Petasis Reaction.

ChemInform ◽  
2010 ◽  
Vol 33 (45) ◽  
pp. no-no
Author(s):  
Tobias Koolmeister ◽  
Mikael Soedergren ◽  
Martin Scobie
Keyword(s):  
Petasis Reaction ◽  
Boronic Esters

Pinacolyl boronic esters as components in the Petasis reaction

2002 ◽  
Vol 43 (34) ◽  
pp. 5965-5968 ◽  
Author(s):  
Tobias Koolmeister ◽  
Mikael Södergren ◽  
Martin Scobie
Keyword(s):  
Petasis Reaction ◽  
Boronic Esters

An Iron-Based Catalyst Enables The Enantioconvergent Synthesis of Chiral 1,1-Diarylalkanes Through a Suzuki-Miyaura Cross-Coupling Reaction

2020 ◽  
Author(s):  
Chet Tyrol ◽  
Nang Yone ◽  
Connor Gallin ◽  
Jeffery Byers
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Radical Intermediates ◽  
Cross Coupling Reactions ◽  
Cross Coupling Reaction ◽  
Boronic Esters ◽  
Carbon Centered Radical ◽  
Iron Based ◽  
High Yields

By using an iron-based catalyst, access to enantioenriched 1,1-diarylakanes was enabled through an enantioselective Suzuki-Miyaura crosscoupling reaction. The combination of a chiral cyanobis(oxazoline) ligand framework and 1,3,5-trimethoxybenzene additive were essential to afford high yields and enantioselectivities in cross-coupling reactions between unactivated aryl boronic esters and a variety of benzylic chlorides, including challenging ortho-substituted benzylic chloride substrates. Mechanistic investigations implicate a stereoconvergent pathway involving carbon-centered radical intermediates.

scholarly journals Asymmetric Catalysis with MOFs Prepared via Chiral Induction Effect

Synfacts ◽  
2010 ◽  
Vol 2011 (01) ◽  
pp. 0105-0105
Author(s):  
C. Duan ◽  
D. Dang ◽  
P. Wu ◽  
C. He ◽  
Z. Xie
Keyword(s):  
Asymmetric Catalysis ◽  
Induction Effect ◽  
Chiral Induction

scholarly journals Chan–Lam Amination of Secondary and Tertiary Benzylic Boronic Esters

2021 ◽  
Author(s):  
James D. Grayson ◽  
Francesca M. Dennis ◽  
Craig C. Robertson ◽  
Benjamin M. Partridge
Keyword(s):  
Boronic Esters

A cycloaddition route to novel triazole boronic esters

2009 ◽  
pp. 436-438 ◽  
Author(s):  
Jianhui Huang ◽  
Simon J. F. Macdonald ◽  
Joseph P. A. Harrity
Keyword(s):  
Boronic Esters

ChemInform Abstract: Direct Synthesis of Functionalized Allylic Boronic Esters from Allylic Alcohols and Inexpensive Reagents and Catalysts.

ChemInform ◽  
2008 ◽  
Vol 39 (48) ◽  
Author(s):  
Guillaume Dutheuil ◽  
Nicklas Selander ◽  
Kalman J. Szabo ◽  
Varinder K. Aggarwal
Keyword(s):  
Direct Synthesis ◽  
Allylic Alcohols ◽  
Boronic Esters

A new nonenzymatic chiral induction into prochiral meso compounds

Tetrahedron ◽  
1984 ◽  
Vol 40 (8) ◽  
pp. 1215-1223 ◽  
Author(s):  
Yoshimitsu nagao ◽  
Takemsa inoue ◽  
Eiichi fujita ◽  
Shunji Terada ◽  
Motoo shiro
Keyword(s):  
Chiral Induction
Sign in / Sign up

Export Citation Format

Share Document