99/00344 Initial carbon-carbon bond formation during synthesis gas conversion to higher alcohols on KCu Mg5CeOx catalyst

1999 ◽  
Vol 40 (1) ◽  
pp. 34
Keyword(s):  
Synthesis Gas ◽  
Bond Formation ◽  
Higher Alcohols ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Initial Carbon ◽  
Synthesis Gas Conversion ◽  
Gas Conversion

scholarly journals Initial Carbon−Carbon Bond Formation during the Early Stages of Methane Dehydroaromatization

2020 ◽  
Author(s):  
Mustafa Çağlayan ◽  
Alessandra Lucini Paioni ◽  
Edy Abou‐Hamad ◽  
Genrikh Shterk ◽  
Alexey Pustovarenko ◽  
...  
Keyword(s):  
Bond Formation ◽  
Carbon Bond ◽  
Early Stages ◽  
Carbon Carbon Bond ◽  
Initial Carbon ◽  
Methane Dehydroaromatization

scholarly journals Initial Carbon–Carbon Bond Formation during the Early Stages of the Methanol‐to‐Olefin Process Proven by Zeolite‐Trapped Acetate and Methyl Acetate

2016 ◽  
Vol 55 (51) ◽  
pp. 15840-15845 ◽  
Author(s):  
Abhishek Dutta Chowdhury ◽  
Klaartje Houben ◽  
Gareth T. Whiting ◽  
Mohamed Mokhtar ◽  
Abdullah M. Asiri ◽  
...  
Keyword(s):  
Methyl Acetate ◽  
Bond Formation ◽  
Carbon Bond ◽  
Early Stages ◽  
Carbon Carbon Bond ◽  
Initial Carbon ◽  
Methanol To Olefin

scholarly journals Innenrücktitelbild: Initial Carbon-Carbon Bond Formation during the Early Stages of the Methanol-to-Olefin Process Proven by Zeolite-Trapped Acetate and Methyl Acetate (Angew. Chem. 51/2016)

2016 ◽  
Vol 128 (51) ◽  
pp. 16161-16161
Author(s):  
Abhishek Dutta Chowdhury ◽  
Klaartje Houben ◽  
Gareth T. Whiting ◽  
Mohamed Mokhtar ◽  
Abdullah M. Asiri ◽  
...  
Keyword(s):  
Methyl Acetate ◽  
Bond Formation ◽  
Carbon Bond ◽  
Early Stages ◽  
Carbon Carbon Bond ◽  
Initial Carbon ◽  
Methanol To Olefin

scholarly journals Initial Carbon−Carbon Bond Formation during the Early Stages of Methane Dehydroaromatization

2020 ◽  
Vol 59 (38) ◽  
pp. 16741-16746 ◽  
Author(s):  
Mustafa Çağlayan ◽  
Alessandra Lucini Paioni ◽  
Edy Abou‐Hamad ◽  
Genrikh Shterk ◽  
Alexey Pustovarenko ◽  
...  
Keyword(s):  
Bond Formation ◽  
Carbon Bond ◽  
Early Stages ◽  
Carbon Carbon Bond ◽  
Initial Carbon ◽  
Methane Dehydroaromatization

scholarly journals Initial Carbon-Carbon Bond Formation during the Early Stages of the Methanol-to-Olefin Process Proven by Zeolite-Trapped Acetate and Methyl Acetate

2016 ◽  
Vol 128 (51) ◽  
pp. 16072-16077 ◽  
Author(s):  
Abhishek Dutta Chowdhury ◽  
Klaartje Houben ◽  
Gareth T. Whiting ◽  
Mohamed Mokhtar ◽  
Abdullah M. Asiri ◽  
...  
Keyword(s):  
Methyl Acetate ◽  
Bond Formation ◽  
Carbon Bond ◽  
Early Stages ◽  
Carbon Carbon Bond ◽  
Initial Carbon ◽  
Methanol To Olefin

Activity and Selectivity Trends in Synthesis Gas Conversion to Higher Alcohols

2013 ◽  
Vol 57 (1-4) ◽  
pp. 135-142 ◽  
Author(s):  
Andrew J. Medford ◽  
Adam C. Lausche ◽  
Frank Abild-Pedersen ◽  
Burcin Temel ◽  
Niels C. Schjødt ◽  
...  
Keyword(s):  
Synthesis Gas ◽  
Higher Alcohols ◽  
Synthesis Gas Conversion ◽  
Gas Conversion

A Mechanistic Study of Syngas to Light Olefins over OXZEO Bifunctional Catalysts: Insights into the Initial Carbon-Carbon Bond Formation on the Oxide

2022 ◽  
Author(s):  
Hongyu Chen ◽  
Zhengmao Liu ◽  
Na Li ◽  
Feng Jiao ◽  
Yuxiang Chen ◽  
...  
Keyword(s):  
Bond Formation ◽  
Direct Conversion ◽  
Bifunctional Catalyst ◽  
Light Olefins ◽  
Mechanistic Study ◽  
Bifunctional Catalysts ◽  
Reaction Intermediates ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Initial Carbon

Direct conversion of syngas into light olefins (C2=-C4=) using bifunctional catalyst composed of oxide and zeolite (OXZEO) has attracted extensive attention in both academia and industry. However, the reaction intermediates...

Carbon Dioxide-Mediated C(sp2)–H Arylation of Primary and Secondary Benzylamines

2018 ◽  
Author(s):  
Mohit Kapoor ◽  
Pratibha Chand-Thakuri ◽  
Michael Young
Keyword(s):  
Carbon Dioxide ◽  
Transition Metal ◽  
Bond Activation ◽  
Bond Formation ◽  
Carbon Bond ◽  
Chelate Effect ◽  
Free Amine ◽  
Carbon Carbon Bond ◽  
New Strategy ◽  
Metal Catalyzed

Carbon-carbon bond formation by transition metal-catalyzed C–H activation has become an important strategy to fabricate new bonds in a rapid fashion. Despite the pharmacological importance of <i>ortho</i>-arylbenzylamines, however, effective <i>ortho</i>-C–C bond formation from C–H bond activation of free primary and secondary benzylamines using Pd<sup>II</sup> remains an outstanding challenge. Presented herein is a new strategy for constructing <i>ortho</i>-arylated primary and secondary benzylamines mediated by carbon dioxide (CO<sub>2</sub>). The use of CO<sub>2</sub> is critical to allowing this transformation to proceed under milder conditions than previously reported, and that are necessary to furnish free amine products that can be directly used or elaborated without the need for deprotection. In cases where diarylation is possible, a chelate effect is demonstrated to facilitate selective monoarylation.

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