Silica immobilized Ru complexes with a different nuclear number as catalysts of the hydrodehalogenation reaction

Author(s):  
V. Isaeva ◽  
Y. Smirnova ◽  
V. Sharf
Keyword(s):  
2019 ◽  
Author(s):  
Victoria A. Ternes ◽  
Hannah A. Morgan ◽  
Austin P. Lanquist ◽  
Michael P. Murray ◽  
Bradley Wile

Herein we report the preparation of a series of Ru(II) complexes featuring alpha-iminopyridine ligands bearing thioether functionality (NNS<sup>R</sup>, where R = Me, CH<sub>2</sub>Ph, Ph). Metallation using (<i>p</i> cymene)RuCl dimer permits access to (k<sup>2</sup>-N,N)Ru complexes in which the thioether moiety remains uncoordinated. In the presence of a strong field ligand such as acetonitrile or triphenylphosphine, the p-cymene moiety is displaced, and the ligand adopts a k<sup>3</sup>-N,N,S binding mode. These complexes are characterized using a combination of solution and solid state methods, including the crystal structure of [(NNS<sup>Me</sup>)Ru(NCMe)<sub>2</sub>Cl]Cl. The k<sup>2</sup>-N,N Ru(II) complexes are shown to serve as efficient precatalysts for the oxidation of sec-phenethyl alcohol at 5 mol% loadings, using a variety of external oxidants and solvents. The complex bearing an S-Ph donor was found to be the most active of those surveyed, suggesting that the thioether donor plays an active role in catalyst speciation for this transformation.


1992 ◽  
Vol 57 (6) ◽  
pp. 1291-1298 ◽  
Author(s):  
František Adámek ◽  
Milan Hájek ◽  
Zbyněk Janoušek

Relative reactivity of CH3CCl3 and CF3CCl3 measured in competitive addition reactions with 1-hexene in the presence of free radical initiators or Cu, Pd and Ru complexes was found to depend on the type of catalyst. The unusual course of the reaction has been found in the additions catalyzed with copper(I)-amine complexes where CH3CCl3 in competition with CF3CCl3 was completely unreactive. The results have been explained in terms of the change of reaction mechanism and compared with classical free radical initiation.


2021 ◽  
Vol 60 (9) ◽  
pp. 6852-6852
Author(s):  
Md Asmaul Hoque ◽  
Abhishek Dutta Chowdhury ◽  
Somnath Maji ◽  
Jordi Benet-Buchholz ◽  
Mehmed Z. Ertem ◽  
...  

2000 ◽  
pp. 217-218 ◽  
Author(s):  
Stephan Steines ◽  
Birgit Drießen-Hölscher ◽  
Ulli Englert

Nematology ◽  
2000 ◽  
Vol 2 (1) ◽  
pp. 71-79 ◽  
Author(s):  
Armand Leroi ◽  
Scott Emmons ◽  
Ana Cunha ◽  
Ricardo B.R. Azevedo

AbstractNematodes are generally considered to have an adult cell number that does not vary among wildtype individuals as a consequence of invariant cell lineages (eutely). However, there is extensive evidence that at least some cell lineages can be variable in nematodes. In a comparative study of 13 free-living nematode species, we have shown that the adult epidermis of most species contained variable numbers of nuclei and that this variance was positively correlated with mean epidermal nuclear number. Here we present simulations of the lateral seam cell lineages of four species and show that variance in cell number is influenced by lineage topology, as well as by the frequency of lineage variants. We show that the epidermal variability of Panagrellus redivivus cannot be accounted for by the complexity of its lineage, but requires higher levels of lineage variability than are found in Caenorhabditis elegans, Oscheius myriophila and Rhabditella octopleura. Our findings suggest that many nematodes may have tissues composed of indeterminate numbers of cells formed from variable lineages and, as such, resemble other metazoans. Les nématodes sont généralement considérés comme ayant un nombre de cellules invariable chez les individus de type sauvage, conséquence d’un lignage cellulaire fixe (eutélie). Cependant, il est d’évidence qu’au moins certains des lignages cellulaires peuvent varier chez les nématodes. Dans une étude comparative portant sur 13 espèces de nématodes libres, nous avions montré que l’épiderme de la plupart de ces espèces comportait un nombre variable de noyaux et que cette variabilité était corrélée positivement avec le nombre de noyaux épidermiques. Nous présentons ici des simulations des lignages cellulaires de la suture latérale de quatre espèces et démontrons que le nombre de cellules est influencé tant par la topologie du lignage que par la fréquence des variants de ce lignage. Nous montrons que la variabilité de l’épiderme de Panagrellus redivivus ne peut être mise au compte de la complexité de son lignage, mais demande des niveaux élevés de variabilité de ce lignage, tels ceux trouvés chez Caenorhabditis elegans, Oscheius myriophila et Rhabditella octopleura. Nos observations suggèrent que nombre de nématodes possèdent des tissus composés d’un nombre indéterminé de cellules dérivant de lignages variables et, de ce fait, ressemblent aux autres metazoaires.


2014 ◽  
Vol 43 (17) ◽  
pp. 6561 ◽  
Author(s):  
Wei-Bin Yu ◽  
Qing-Ya He ◽  
Hua-Tian Shi ◽  
Juan-Ying Jia ◽  
Xianwen Wei

ChemInform ◽  
2010 ◽  
Vol 25 (19) ◽  
pp. no-no
Author(s):  
V. I. ISAEVA ◽  
YA. V. SMIRNOVA ◽  
V. Z. SHARF
Keyword(s):  

Nanomedicine ◽  
2018 ◽  
Vol 13 (21) ◽  
pp. 2691-2708 ◽  
Author(s):  
Jun-Jie Xue ◽  
Fahime Bigdeli ◽  
Jian-Ping Liu ◽  
Mao-Lin Hu ◽  
Ali Morsali

1998 ◽  
Vol 27 (2) ◽  
pp. 123-124 ◽  
Author(s):  
Jose Giner Planas ◽  
Masafumi Hirano ◽  
Sanshiro Komiya
Keyword(s):  

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