Chemoselective Hydrogenation of Aromatic Chloronitro Compounds with Amidine Modified Nickel Catalysts.

Author(s):  
P. Baumeister ◽  
H.U. Blaser ◽  
W. Scherrer
2013 ◽  
Vol 33 (7) ◽  
pp. 1176-1182
Author(s):  
Xinxing WANG ◽  
Xueguang WANG ◽  
Xingfu SHANG ◽  
Wangxin NIE ◽  
Xiujing ZOU ◽  
...  

1969 ◽  
Vol 34 (9) ◽  
pp. 2652-2661
Author(s):  
L. Scháněl ◽  
P. Schneider ◽  
V. Bažant

1998 ◽  
Vol 63 (11) ◽  
pp. 1945-1953 ◽  
Author(s):  
Jiří Hanika ◽  
Karel Sporka ◽  
Petr Macoun ◽  
Vladimír Kysilka

The activity of ruthenium, palladium, and nickel catalysts for the hydrogenation of 1,2-dihydroacenaphthylene in cyclohexane solution was studied at temperatures up to 180 °C and pressures up to 8 MPa. The GC-MS technique was used to identify most of the perhydroacenaphthylene stereoisomers, whose fractions in the product were found dependent on the nature of the active component of the catalyst. The hydrogenation was fastest on the palladium catalyst (3% Pd/C). The nickel catalyst Ni-NiO/Al2O3, which is sufficiently active also after repeated use, can be recommended for practical application. The activation energy of 1,2-dihydroacenaphthylene hydrogenation using this catalyst is 17 kJ/mol, the reaction order with respect to hydrogen is unity.


2020 ◽  
Vol 607 ◽  
pp. 117779 ◽  
Author(s):  
Dara Khairunnisa Binte Mohamed ◽  
Andrei Veksha ◽  
Teik-Thye Lim ◽  
Grzegorz Lisak

RSC Advances ◽  
2020 ◽  
Vol 10 (72) ◽  
pp. 44191-44195
Author(s):  
Chandan Chaudhari ◽  
Katsutoshi Sato ◽  
Yoshihide Nishida ◽  
Tomokazu Yamamoto ◽  
Takaaki Toriyama ◽  
...  

Recyclable Pd0.5Ru0.5–PVP catalyst showed higher activity than monometallic Pd or Ru catalyst for the hydrogenation of quinoline. Furthermore, Pd0.5Ru0.5–PVP was able to hydrogenate different arenes.


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