Activity and selectivity of Group VIII, alkali-promoted Mn-Ni, and Mo-based catalysts for C2+ oxygenate synthesis from the CO hydrogenation and CO/H2/C2H4 reactions

2000 ◽  
Vol 55 (3) ◽  
pp. 247-257 ◽  
Author(s):  
S.A. Hedrick ◽  
S.S.C. Chuang ◽  
A. Pant ◽  
A.G. Dastidar
Keyword(s):  
Co Hydrogenation ◽  
Group Viii ◽  
Oxygenate Synthesis

Highly active carbon nanotube–promoted Rh-Mn-Li/SiO2 catalysts for the synthesis of C2+ oxygenates from syngas

2021 ◽  
pp. 174751982098472
Author(s):  
Jun Yu ◽  
Ying Han ◽  
Guoqing Chen ◽  
Xiuzhen Xiao ◽  
Haifang Mao ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Photoelectron Spectroscopy ◽  
Co Hydrogenation ◽  
X Ray ◽  
Highly Active ◽  
Transmission Electron ◽  
Co Insertion ◽  
Temperature Programmed Surface Reaction ◽  
Temperature Programmed ◽  
Oxygenate Synthesis

The effect of carbon nanotubes on the catalytic properties of Rh-Mn-Li/SiO2 catalysts was investigated for CO hydrogenation. The catalysts were comprehensively characterized by means of X-ray power diffraction, N2 sorption, transmission electron microscope, H2–temperature-programmed reduction, CO–temperature-programmed desorption, temperature-programmed surface reaction, and X-ray photoelectron spectroscopy. The results showed that an appropriate amount of carbon nanotubes can be attached to the surface of the SiO2 sphere and can improve the Rh dispersion. Moderate Rh-Mn interaction can be obtained by doping with the appropriate amount of carbon nanotubes, which promotes the formation of strongly adsorbed CO and facilitates the progress of CO insertion, resulting in the increase in the selectivity of C2+ oxygenate synthesis.

CO Hydrogenation on Pd(111): Competition between Fischer–Tropsch and Oxygenate Synthesis Pathways

2013 ◽  
Vol 117 (28) ◽  
pp. 14667-14676 ◽  
Author(s):  
Sen Lin ◽  
Jianyi Ma ◽  
Xinxin Ye ◽  
Daiqian Xie ◽  
Hua Guo
Keyword(s):  
Co Hydrogenation ◽  
Fischer Tropsch ◽  
Oxygenate Synthesis

Kinetics of CO hydrogenation on group VIII metals

1986 ◽  
Vol 32 (2) ◽  
pp. 481-485 ◽  
Author(s):  
G. I. Golodets ◽  
N. V. Pavlenko ◽  
A. I. Tripolskii
Keyword(s):  
Co Hydrogenation ◽  
Group Viii ◽  
Kinetics Of

Enhanced C2 oxygenate synthesis by CO hydrogenation over Rh-based catalyst supported on a novel SiO2

2012 ◽  
Vol 24 ◽  
pp. 25-29 ◽  
Author(s):  
Jun Yu ◽  
Dongsen Mao ◽  
Guanzhong Lu ◽  
Qiangsheng Guo ◽  
Lupeng Han
Keyword(s):  
Co Hydrogenation ◽  
Oxygenate Synthesis

C2 oxygenate synthesis from CO hydrogenation on AgRh/SiO2

1990 ◽  
Vol 57 (1) ◽  
pp. 241-251 ◽  
Author(s):  
Steven S.C. Chuang ◽  
Shyh-Ing Pien ◽  
Ravi Narayanan
Keyword(s):  
Co Hydrogenation ◽  
Oxygenate Synthesis

Binding of Group Viii Ions to a Polyacrylonitrile Matrix

2021 ◽  
Author(s):  
R. F. Vitkovskaya ◽  
I. G. Rumynskaya ◽  
L. N. Bykov ◽  
V. V. Samonin ◽  
N. P. Novoselov
Keyword(s):  
Group Viii

scholarly journals The interaction of size-selected Ru3 clusters with RF-deposited TiO2: probing Ru-CO binding sites with CO-Temperature Programmed Desorption

2021 ◽  
Author(s):  
Liam Howard-Fabretto ◽  
Timothy Gorey ◽  
Guangjing Li ◽  
Siriluck Tesana ◽  
Gregory F Metha ◽  
...  
Keyword(s):  
Radio Frequency ◽  
Chemical Reactions ◽  
Binding Sites ◽  
Co Hydrogenation ◽  
Temperature Programmed Desorption ◽  
Temperature Programmed

Small Ru clusters are efficient catalysts for chemical reactions such as CO hydrogenation. In this study 3-atom Ru3 clusters were deposited onto radio frequency (RF)-deposited TiO2 which is an inexpensive,...

Study on the co-hydrogenation of coal tar and kitchen waste oil over Co–Mo/γ–Al2O3

2021 ◽  
Author(s):  
Panpan Ji ◽  
Zheng Fan ◽  
Menglong Niu ◽  
Liuyi Pan ◽  
Genhui Jing ◽  
...  
Keyword(s):  
Co Hydrogenation ◽  
Coal Tar ◽  
Waste Oil ◽  
Kitchen Waste
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