A kinetic investigation of styrene emulsion polymerization with surface active polyelectrolytes as the emulsifier. II: effects of molecular weight and composition

1999 ◽  
Vol 153 (1-3) ◽  
pp. 127-131 ◽  
Author(s):  
Satoshi Kato ◽  
Kazuhiro Sato ◽  
Daiharu Maeda ◽  
Mamoru Nomura
Keyword(s):  
Molecular Weight ◽  
Emulsion Polymerization ◽  
Kinetic Investigation ◽  
Surface Active

Simulation of Polymerization Kinetics and Molecular Weight Development in the Microwave-Activated Emulsion Polymerization of Styrene using EMULPOLY®

2010 ◽  
Vol 33 (11) ◽  
pp. 1888-1892 ◽  
Author(s):  
G. Jaramillo-Soto ◽  
M. Ramírez-Cupido ◽  
J. A. Tenorio-López ◽  
E. Vivaldo-Lima ◽  
A. Penlidis
Keyword(s):  
Molecular Weight ◽  
Emulsion Polymerization ◽  
Polymerization Kinetics

Molecular weight distribution in emulsion polymerization. I. The homopolymer case

1992 ◽  
Vol 30 (5) ◽  
pp. 731-750 ◽  
Author(s):  
Giuseppe Storti ◽  
Gianmarco Polotti ◽  
Michele Cociani ◽  
Massimo Morbidelli
Keyword(s):  
Molecular Weight ◽  
Emulsion Polymerization ◽  
Molecular Weight Distribution ◽  
Weight Distribution

Amphiphilic Block Copolymers as Stabilizers in Emulsion Polymerization: Effects of the Anchoring Block Molecular Weight Dispersity on Stabilization Performance

2016 ◽  
Vol 50 (1) ◽  
pp. 315-323 ◽  
Author(s):  
Sean R. George ◽  
Rachel Champagne-Hartley ◽  
Gary A. Deeter ◽  
J. D. Campbell ◽  
Bernd Reck ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Block Copolymers ◽  
Emulsion Polymerization ◽  
Amphiphilic Block Copolymers

Synthesis and use of a surface-active initiator in emulsion polymerization under AGET and ARGET ATRP conditions

2010 ◽  
Vol 34 (1) ◽  
pp. 163-170 ◽  
Author(s):  
Chuanjie Cheng ◽  
Jinbing Shu ◽  
Shanshan Gong ◽  
Liang Shen ◽  
Yongluo Qiao ◽  
...  
Keyword(s):  
Emulsion Polymerization ◽  
Arget Atrp ◽  
Surface Active ◽  
Active Initiator

A kinetic investigation of surfactant-free emulsion polymerization of styrene using laponite clay platelets as stabilizers

2011 ◽  
Vol 49 (22) ◽  
pp. 4771-4784 ◽  
Author(s):  
Nida Sheibat-Othman ◽  
Ana-Maria Cenacchi-Pereira ◽  
Amilton Martins Dos Santos ◽  
Elodie Bourgeat-Lami
Keyword(s):  
Emulsion Polymerization ◽  
Kinetic Investigation ◽  
Clay Platelets

scholarly journals Effect of Oxygen and Initiator Solubility on Admicellar Polymerization of Styrene on Silica Surfaces

2017 ◽  
Vol 2017 ◽  
pp. 1-7 ◽  
Author(s):  
Pohlee Cheah ◽  
Caitlin N. Bhikha ◽  
John H. O’Haver ◽  
Adam E. Smith
Keyword(s):  
Molecular Weight ◽  
Free Radical ◽  
Emulsion Polymerization ◽  
Water Soluble ◽  
Polymer Yield ◽  
Radical Initiator ◽  
Admicellar Polymerization ◽  
Molecular Weights ◽  
Precipitated Silica ◽  
Free Radical Initiator

Although admicellar polymerization has been termed the surface analog of emulsion polymerization, previous reports utilizing free radical-initiated admicellar polymerization relied on high levels of the free radical initiator when compared to emulsion polymerization, likely due to the presence of oxygen in the reported admicellar polymerization systems. Admicellar polymerizations of styrene on the surface of precipitated silica initiated by either a water-soluble or a water-insoluble initiator were studied to determine the effect of dissolved oxygen and free radical initiator solubility on the kinetics, yield, and molecular weight of the polymer formed. Results show that the presence of oxygen reduces the polymer yield and limits molecular weight. The solubility of the initiator also affected the polymer formed in the admicellar polymerization of styrene. While monomer conversions and polymer yield were similar, the molecular weights of polymerizations initiated by a water-soluble initiator were higher than comparable polymerizations initiated by a water-insoluble initiator.

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