Two reactions of allylic alcohols catalysed by ruthenium cyclopentadienyl complexes with didentate phosphine ligands: isomerisation and ether formation

2000 ◽  
Vol 159 (2) ◽  
pp. 163-177 ◽  
Author(s):  
Robert C. van der Drift ◽  
Matteo Vailati ◽  
Elisabeth Bouwman ◽  
Eite Drent
Keyword(s):  
Phosphine Ligands ◽  
Allylic Alcohols ◽  
Cyclopentadienyl Complexes

Nickel-Catalyzed Suzuki Cross Couplings with Unprotected Allylic Alcohols Enabled by Bidentate N-Heterocyclic Carbene (NHC)/Phosphine Ligands

ACS Catalysis ◽  
2017 ◽  
Vol 8 (1) ◽  
pp. 86-89 ◽  
Author(s):  
S. Hadi Nazari ◽  
Jefferson E. Bourdeau ◽  
Michael R. Talley ◽  
Gabriel A. Valdivia-Berroeta ◽  
Stacey J. Smith ◽  
...  
Keyword(s):  
Phosphine Ligands ◽  
Allylic Alcohols

Scope, mechanism and diene inhibition of isomerization of allylic alcohols to saturated ketones catalyzed by ruthenium(II)-cyclopentadienyl complexes

2005 ◽  
Vol 690 (4) ◽  
pp. 1044-1055 ◽  
Author(s):  
Robert C. van der Drift ◽  
Marcella Gagliardo ◽  
Huub Kooijman ◽  
Anthony L. Spek ◽  
Elisabeth Bouwman ◽  
...  
Keyword(s):  
Allylic Alcohols ◽  
Cyclopentadienyl Complexes

Active MnO2 As a Mild Oxidizing Reagent for the Controlled Oxidation of Benzylic and Allylic Alcohols

2012 ◽  
Vol 2 (6) ◽  
pp. 48-48
Author(s):  
Y. M. Nandurkar Y. M. Nandurkar ◽  
◽  
B. B. Bahule B. B. Bahule
Keyword(s):  
Allylic Alcohols

Bimetallic Radical Redox-Relay Catalysis for the Isomerization of Epoxides to Allylic Alcohols

2019 ◽  
Author(s):  
Ke-Yin Ye ◽  
Terry McCallum ◽  
Song Lin
Keyword(s):  
Ring Opening ◽  
High Reactivity ◽  
Hydrogen Atom Transfer ◽  
Organic Radicals ◽  
Epoxide Ring ◽  
Allylic Alcohols ◽  
Epoxide Ring Opening ◽  
Bond Forming ◽  
Co Catalysts ◽  
The Rich

Organic radicals are generally short-lived intermediates with exceptionally high reactivity. Strategically, achieving synthetically useful transformations mediated by organic radicals requires both efficient initiation and selective termination events. Here, we report a new catalytic strategy, namely bimetallic radical redox-relay, in the regio- and stereoselective rearrangement of epoxides to allylic alcohols. This approach exploits the rich redox chemistry of Ti and Co complexes and merges reductive epoxide ring opening (initiation) with hydrogen atom transfer (termination). Critically, upon effecting key bond-forming and -breaking events, Ti and Co catalysts undergo proton-transfer/electron-transfer with one another to achieve turnover, thus constituting a truly synergistic dual catalytic system.<br>

Direct and Selective Synthesis of Adipic and Other Dicarboxylic Acids by Palladium‐Catalyzed Carbonylation of Allylic Alcohols

2020 ◽  
Vol 59 (46) ◽  
pp. 20394-20398
Author(s):  
Ji Yang ◽  
Jiawang Liu ◽  
Yao Ge ◽  
Weiheng Huang ◽  
Helfried Neumann ◽  
...  
Keyword(s):  
Dicarboxylic Acids ◽  
Allylic Alcohols ◽  
Selective Synthesis ◽  
Palladium Catalyzed
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