Determination of cyanide in its platinum and palladium complexes

1974 ◽  
Vol 46 (1) ◽  
pp. 170-171 ◽  
Author(s):  
Bernard L. Gilbert ◽  
Bert L. Olson ◽  
Wilhad. Reuter



1993 ◽  
Vol 206 (1) ◽  
pp. 123-125 ◽  
Author(s):  
Xu Chongfu ◽  
Jeffrey W. Siria ◽  
Gordon K. Anderson


2012 ◽  
Vol 31 (7) ◽  
pp. 2854-2877 ◽  
Author(s):  
Paul D. Zeits ◽  
Giovanni Pietro Rachiero ◽  
Frank Hampel ◽  
Joseph H. Reibenspies ◽  
John A. Gladysz


2015 ◽  
Vol 11 ◽  
pp. 1175-1186 ◽  
Author(s):  
Rym Hassani ◽  
Mahjoub Jabli ◽  
Yakdhane Kacem ◽  
Jérôme Marrot ◽  
Damien Prim ◽  
...  

The present paper describes the synthesis of new palladium–oxazoline complexes in one step with good to high yields (68–95%). The oxazolines were prepared from enantiomerically pure α-aminoalcohols. The structures of the synthesized palladium complexes were confirmed by NMR, FTIR, TOFMS, UV–visible spectroscopic analysis and X–ray diffraction. The optical properties of the complexes were evaluated by the determination of the gap energy values (E g) ranging between 2.34 and 3.21 eV. Their catalytic activities were tested for the degradation of Eriochrome Blue Black B (a model of azo dyes) in the presence of an ecological oxidant (H2O2). The efficiency of the decolorization has been confirmed via UV–visible spectroscopic analysis and the factors affecting the degradation phenomenon have been studied. The removal of the Eriochrome reached high yields. We have found that the complex 9 promoted 84% of color elimination within 5 min (C 0 = 30 mg/L, T = 22 °C, pH 7, H2O2 = 0.5 mL) and the energetic parameters have been also determined.



2018 ◽  
Vol 42 (8) ◽  
pp. 6264-6273 ◽  
Author(s):  
H. R. Rajegowda ◽  
P. Raghavendra Kumar ◽  
Amar Hosamani ◽  
R. J. Butcher

Enantiomerically pure chiral hybrid organotellurium ligands and their asymmetric palladium complexes have been synthesized and characterized.



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