Bis-Palladium Complex of α-Benzimidazole 9-Pyrrolyl Dipyrromethene: Synthesis, Structure, and Spectral and Catalytic Properties

Author(s):  
Sabari Panchavarnam ◽  
Rima Sengupta ◽  
Mangalampalli Ravikanth
2001 ◽  
Vol 4 (9) ◽  
pp. 471-474 ◽  
Author(s):  
Jairton Dupont ◽  
Gunter Ebeling ◽  
Marcelo R. Delgado ◽  
Crestina S. Consorti ◽  
Robert Burrow ◽  
...  

2013 ◽  
Vol 36 ◽  
pp. 245-248 ◽  
Author(s):  
Jing Chu ◽  
Qi-ying Lv ◽  
Jie-ping Cao ◽  
Xiao-hua Xie ◽  
Shuzhong Zhan

2011 ◽  
Vol 332-334 ◽  
pp. 1900-1903 ◽  
Author(s):  
Quan Chen ◽  
Rui Xu ◽  
Da Hu Yao

A fiber-supported palladium catalyst was synthesized simply by amidoximation reaction from poly (acrylonitrile/vinylamine)(PANVAm) fiber. The structure and properties of the catalyst were characterized XPS. High efficiency of the catalyst along with its recycling ability was demonstrated in the Heck reaction.


2008 ◽  
Vol 350 (11-12) ◽  
pp. 1791-1795 ◽  
Author(s):  
Tao Tu ◽  
Jagadeesh Malineni ◽  
Karl Heinz Dötz

Author(s):  
L.D. Schmidt ◽  
K. R. Krause ◽  
J. M. Schwartz ◽  
X. Chu

The evolution of microstructures of 10- to 100-Å diameter particles of Rh and Pt on SiO2 and Al2O3 following treatment in reducing, oxidizing, and reacting conditions have been characterized by TEM. We are able to transfer particles repeatedly between microscope and a reactor furnace so that the structural evolution of single particles can be examined following treatments in gases at atmospheric pressure. We are especially interested in the role of Ce additives on noble metals such as Pt and Rh. These systems are crucial in the automotive catalytic converter, and rare earths can significantly modify catalytic properties in many reactions. In particular, we are concerned with the oxidation state of Ce and its role in formation of mixed oxides with metals or with the support. For this we employ EELS in TEM, a technique uniquely suited to detect chemical shifts with ∼30Å resolution.


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