Magnetic Relaxation Dynamics of a Centrosymmetric Dy2 Single-Molecule Magnet Triggered by Magnetic-Site Dilution and External Magnetic Field

2017 ◽  
Vol 56 (10) ◽  
pp. 5611-5622 ◽  
Author(s):  
Hui-Ming Dong ◽  
Hai-Yan Li ◽  
Yi-Quan Zhang ◽  
En-Cui Yang ◽  
Xiao-Jun Zhao
Keyword(s):  
Magnetic Field ◽  
External Magnetic Field ◽  
Single Molecule ◽  
Magnetic Relaxation ◽  
Relaxation Dynamics ◽  
Single Molecule Magnet

An air stable radical-bridged dysprosium single molecule magnet and its neutral counterpart: redox switching of magnetic relaxation dynamics

2017 ◽  
Vol 53 (14) ◽  
pp. 2283-2286 ◽  
Author(s):  
Brian S. Dolinar ◽  
Silvia Gómez-Coca ◽  
Dimitris I. Alexandropoulos ◽  
Kim R. Dunbar
Keyword(s):  
Magnetic Properties ◽  
Single Molecule ◽  
Quantum Tunneling ◽  
Magnetic Relaxation ◽  
Thermal Relaxation ◽  
Relaxation Dynamics ◽  
Single Molecule Magnet ◽  
Neutral Compound ◽  
Redox Switching ◽  
P Addition

Addition of a radical to the bridging tetrazine ligand of a Dy2 complex dramatically alters the magnetic properties. The radical complex undergoes magnetic relaxation via a thermal relaxation pathway, whereas the neutral compound relaxes via quantum tunneling of the magnetization.

A Nonsymmetric Dy2 Single-Molecule Magnet with two Relaxation Processes Triggered by External Magnetic Field: Theoretical and Integrated EPR study of the Role of Magnetic-Site Dilution

2022 ◽  
Author(s):  
Nikolia Lalioti ◽  
Vassilis Nastopoulos ◽  
Nikolaos Panayiotou ◽  
Anastasios Tasiopoulos ◽  
Nikolaos Ioannidis ◽  
...  
Keyword(s):  
Magnetic Field ◽  
External Magnetic Field ◽  
Single Molecule ◽  
Good Yield ◽  
Relaxation Processes ◽  
Single Molecule Magnet

The 1:2 reaction between Dy(O2CMe)34H2O and 1-acetyl-2-napthol (LH) in MeOH has provided access to complex [Dy2L6(MeOH)]MeOH (1.MeOH) in good yield. The structures of the isomorphous complexes 1MeOH and its doped...

Magnetic Relaxation of Single-Molecule Magnets in an External Magnetic Field: An Ising Dimer of a Terbium(III)-Phthalocyaninate Triple-Decker Complex

2010 ◽  
Vol 17 (1) ◽  
pp. 117-122 ◽  
Author(s):  
Keiichi Katoh ◽  
Takashi Kajiwara ◽  
Motohiro Nakano ◽  
Yasuhiro Nakazawa ◽  
Wolfgang Wernsdorfer ◽  
...  
Keyword(s):  
Magnetic Field ◽  
External Magnetic Field ◽  
Single Molecule ◽  
Magnetic Relaxation ◽  
Single Molecule Magnets

Modulating the slow magnetic relaxation of a mononuclear Dy(III) single-molecule magnet via magnetic field and dilution effect

CrystEngComm ◽  
2021 ◽  
Author(s):  
Peipei Cen ◽  
Zixin He ◽  
Runmei Ding ◽  
Huifang Yang ◽  
Li Li ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Single Molecule ◽  
Self Assembly ◽  
Magnetic Relaxation ◽  
Dilution Effect ◽  
Crystallographic Data ◽  
Single Molecule Magnet ◽  
Slow Magnetic Relaxation ◽  
Dysprosium Complex

A β-diketonate mononuclear dysprosium complex, with the formula [Dy(dpq)(BTFA)3] (1), has been prepared via self-assembly between 3-benzoyl-1,1,1-trifluoroacetone (BTFA) and dipyrido [3,2-d:2’,3’-f] quinoxaline (dpq) ligands. The crystallographic data reveals that the...

Slow magnetic relaxation in dinuclear dysprosium and holmium phenoxide bridged complexes: a Dy2 single molecule magnet with a high energy barrier

2021 ◽  
Author(s):  
Matilde Fondo ◽  
Julio Corredoira-Vázquez ◽  
Ana M. Garcia-Deibe ◽  
Jesus Sanmartin Matalobos ◽  
Silvia Gómez-Coca ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Single Molecule ◽  
Energy Barrier ◽  
Magnetic Relaxation ◽  
High Energy ◽  
Single Molecule Magnet ◽  
High Energy Barrier ◽  
Slow Magnetic Relaxation

Dinuclear [M(H3L1,2,4)]2 (M = Dy, Dy2; M = Ho, Ho2) complexes were isolated from an heptadentate aminophenol ligand. The crystal structures of Dy2·2THF, and the pyridine adducts Dy2·2Py and Ho2·2Py,...

scholarly journals A Dy(III) Fluorescent Single-Molecule Magnet Based on a Rhodamine 6G Ligand

Inorganics ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 51
Author(s):  
Lin Miao ◽  
Mei-Jiao Liu ◽  
Man-Man Ding ◽  
Yi-Quan Zhang ◽  
Hui-Zhong Kou
Keyword(s):  
Magnetic Properties ◽  
Single Molecule ◽  
Magnetic Relaxation ◽  
Rhodamine 6G ◽  
Bond Angle ◽  
Magnetic Measurements ◽  
Single Molecule Magnet ◽  
Lanthanide Metals ◽  
Process Studies ◽  
Dual Functions

The complexes of lanthanide metals, especially dysprosium, can generally exhibit excellent magnetic properties. By means of modifying ligands, dual functions or even multi-functions can be achieved. Here, we synthesized an eight-coordinate Dy(III) complex 1, [Dy(HL-o)2(MeOH)2](ClO4)3·4.5MeOH, which is single-molecule magnet (SMM), and the introduction of the rhodamine 6G chromophore in the ring-opened ligand HL-o realizes ligand-centered fluorescence in addition to SMM. Magnetic measurements and ab initio calculations indicate that the magnetic relaxation for complex 1 should be due to the Raman relaxation process. Studies on magneto-structural correlationship of the rhodamine salicylaldehyde hydrazone Dy(III) complexes show that the calculated energy of the first Kramers Doublet (EKD1) is basically related to the Ophenoxy-Dy-Ophenoxy bond angle, i.e., the larger Ophenoxy-Dy-Ophenoxy bond angle corresponds to a larger EKD1.

Polyoxometalate-Supported Lanthanoid Single-Molecule Magnets

2014 ◽  
Vol 67 (11) ◽  
pp. 1542 ◽  
Author(s):  
Michele Vonci ◽  
Colette Boskovic
Keyword(s):  
Single Molecule ◽  
Energy Barrier ◽  
Magnetic Relaxation ◽  
Donor Ligands ◽  
Single Molecule Magnets ◽  
Single Molecule Magnet ◽  
Coordination Numbers ◽  
Oxygen Donor ◽  
Slow Magnetic Relaxation

Polyoxometalates are robust and versatile multidentate oxygen-donor ligands, eminently suitable for coordination to trivalent lanthanoid ions. To date, 10 very different structural families of such complexes have been found to exhibit slow magnetic relaxation due to single-molecule magnet (SMM) behaviour associated with the lanthanoid ions. These families encompass complexes with between one and four of the later lanthanoid ions: Tb, Dy, Ho, Er, and Yb. The lanthanoid coordination numbers vary between six and eleven and a range of coordination geometries are evident. The highest energy barrier to magnetisation reversal measured to date for a lanthanoid–polyoxometalate SMM is Ueff/kB = 73 K for the heterodinuclear Dy–Eu compound (Bu4N)8H4[DyEu(OH)2(γ-SiW10O36)2].

Synchronous Temperature and Magnetic Field Dual‐Sensing by Luminescence in a Dysprosium Single‐Molecule Magnet

2021 ◽  
pp. 2101495
Author(s):  
Rute A. S. Ferreira ◽  
Ekaterina Mamontova ◽  
Alexandre M. P. Botas ◽  
Mikhail Shestakov ◽  
Johan Vanacken ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Single Molecule ◽  
Single Molecule Magnet ◽  
Dual Sensing

Regulation of magnetic relaxation behavior by replacing 3d transition metal ions in [M2Dy2] complexes containing two different organic chelating ligands

2019 ◽  
Vol 48 (27) ◽  
pp. 10011-10022 ◽  
Author(s):  
Hui-Sheng Wang ◽  
Cheng-Ling Yin ◽  
Zhao-Bo Hu ◽  
Yong Chen ◽  
Zhi-Quan Pan ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Single Molecule ◽  
Magnetic Relaxation ◽  
Transition Metal Ions ◽  
Relaxation Behavior ◽  
Organic Ligands ◽  
Chelating Ligands ◽  
Single Molecule Magnet

Two [MIII2DyIII2] complexes (M = Fe for 1 and Co for 2) with mixed organic ligands were obtained. Complex 2 exhibits single molecule magnet behavior with Ueff = 64.0(9) K.

Structures, fluorescence properties and magnetic properties of a series of rhombus-shaped LnIII4 clusters: magnetocaloric effect and single-molecule-magnet behavior

2019 ◽  
Vol 43 (33) ◽  
pp. 12941-12949 ◽  
Author(s):  
Wen-Min Wang ◽  
Li Zhang ◽  
Xian-Zhen Li ◽  
Li-Yuan He ◽  
Xin-Xin Wang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Magnetocaloric Effect ◽  
Single Molecule ◽  
Magnetic Relaxation ◽  
Magnetic Refrigeration ◽  
Fluorescence Properties ◽  
Relaxation Processes ◽  
Magnetic Studies ◽  
Single Molecule Magnet ◽  
Slow Magnetic Relaxation

A family LnIII4 clusters were successfully synthesized and structurally characterized. Magnetic studies show that Gd4 cluster displays magnetic refrigeration, while Dy4 cluster demonstrates two distinct slow magnetic relaxation processes.

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