Catalyst-Dependent Selective Hydrogenation of Nitriles: Selective Synthesis of Tertiary and Secondary Amines

2017 ◽  
Vol 82 (20) ◽  
pp. 10939-10944 ◽  
Author(s):  
Yasunari Monguchi ◽  
Masahiro Mizuno ◽  
Tomohiro Ichikawa ◽  
Yuki Fujita ◽  
Eri Murakami ◽  
...  
Keyword(s):  
Selective Hydrogenation ◽  
Secondary Amines ◽  
Selective Synthesis ◽  
Hydrogenation Of Nitriles

Selective synthesis of secondary amines from nitriles using Pt nanowires as a catalyst

2014 ◽  
Vol 50 (26) ◽  
pp. 3512-3515 ◽  
Author(s):  
Shuanglong Lu ◽  
Jiaqing Wang ◽  
Xueqin Cao ◽  
Xinming Li ◽  
Hongwei Gu
Keyword(s):  
Secondary Amines ◽  
Selective Synthesis ◽  
Mild Conditions ◽  
Hydrogenation Of Nitriles ◽  
Pt Nanowires

A series of both symmetrical and unsymmetrical secondary amines are synthesized from hydrogenation of nitriles under mild conditions.

Ruthenium-Catalyzed Transfer Hydrogenation of Nitriles: Reduction and SubsequentN-Monoalkylation to Secondary Amines

2013 ◽  
Vol 2013 (18) ◽  
pp. 3671-3674 ◽  
Author(s):  
Svenja Werkmeister ◽  
Christoph Bornschein ◽  
Kathrin Junge ◽  
Matthias Beller
Keyword(s):  
Transfer Hydrogenation ◽  
Secondary Amines ◽  
Hydrogenation Of Nitriles

ChemInform Abstract: Ruthenium-Catalyzed Transfer Hydrogenation of Nitriles: Reduction and Subsequent N-Monoalkylation to Secondary Amines.

ChemInform ◽  
2013 ◽  
Vol 44 (45) ◽  
pp. no-no
Author(s):  
Svenja Werkmeister ◽  
Christoph Bornschein ◽  
Kathrin Junge ◽  
Matthias Beller
Keyword(s):  
Transfer Hydrogenation ◽  
Secondary Amines ◽  
Hydrogenation Of Nitriles

Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Cobalt Pincer Complex

2015 ◽  
Vol 137 (28) ◽  
pp. 8888-8891 ◽  
Author(s):  
Arup Mukherjee ◽  
Dipankar Srimani ◽  
Subrata Chakraborty ◽  
Yehoshoa Ben-David ◽  
David Milstein
Keyword(s):  
Selective Hydrogenation ◽  
Primary Amines ◽  
Pincer Complex ◽  
Hydrogenation Of Nitriles

A New Supported Rhodium Catalyst for Selective Hydrogenation of Nitriles to Primary Amines

2007 ◽  
Vol 72 (4) ◽  
pp. 468-474 ◽  
Author(s):  
Peter T. Witte
Keyword(s):  
Selective Hydrogenation ◽  
High Selectivity ◽  
Rhodium Catalyst ◽  
Primary Amines ◽  
Mild Conditions ◽  
Pharmaceutical Applications ◽  
Strong Acids ◽  
Hydrogenation Of Nitriles ◽  
Supported Rhodium Catalyst

Nitriles are converted to primary amines with high selectivity using a newly developed alumina-supported rhodium catalyst. The high selectivity is obtained without any additives, which are often used to prevent the formation of higher amines. The catalyst is active under mild conditions in various solvents, which makes it specifically suitable for use in pharmaceutical applications or for other substrates that can react with additives like strong acids or bases.

Selective hydrogenation of nitriles to primary amines catalyzed by a novel iron complex

2016 ◽  
Vol 52 (9) ◽  
pp. 1812-1815 ◽  
Author(s):  
Subrata Chakraborty ◽  
Gregory Leitus ◽  
David Milstein
Keyword(s):  
Selective Hydrogenation ◽  
Iron Complex ◽  
Primary Amines ◽  
Homogeneous Hydrogenation ◽  
Earth Abundant ◽  
Novel Complex ◽  
Aliphatic Nitriles ◽  
Hydrogenation Of Nitriles

A novel complex based on earth-abundant iron, and its application in the catalytic homogeneous hydrogenation of (hetero)aromatic, benzylic, and aliphatic nitriles to selectively form primary amines is discovered.

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