Synthesis of Central Chirality-Containing Triarylmethanols and Triarylmethyl Radicals with Extraordinarily Stable Configurations

2019 ◽  
Vol 84 (18) ◽  
pp. 11774-11782
Author(s):  
Yingchun Li ◽  
Weixiang Zhai ◽  
Yongfang Liao ◽  
Jiangping Nie ◽  
Guifang Han ◽  
...  
1968 ◽  
Vol 90 (16) ◽  
pp. 4225-4231 ◽  
Author(s):  
A. H. Maki ◽  
R. D. Allendoerfer ◽  
J. C. Danner ◽  
R. T. Keys

1967 ◽  
Vol 89 (9) ◽  
pp. 2054-2058 ◽  
Author(s):  
M. J. Sabacky ◽  
C. S. Johnson ◽  
R. G. Smith ◽  
H. S. Gutowsky ◽  
J. C. Martin

2015 ◽  
Vol 119 (43) ◽  
pp. 13630-13640 ◽  
Author(s):  
Andrey A. Kuzhelev ◽  
Dmitry V. Trukhin ◽  
Olesya A. Krumkacheva ◽  
Rodion K. Strizhakov ◽  
Olga Yu. Rogozhnikova ◽  
...  

2017 ◽  
Vol 231 (4) ◽  
Author(s):  
Andrey A. Kuzhelev ◽  
Victor M. Tormyshev ◽  
Olga Yu. Rogozhnikova ◽  
Dmitry V. Trukhin ◽  
Tatiana I. Troitskaya ◽  
...  

AbstractTriarylmethyl (TAM) radicals are widely used in electron paramagnetic resonance (EPR) spectroscopy as spin labels and in EPR imaging as spin probes for


Molecules ◽  
2019 ◽  
Vol 24 (4) ◽  
pp. 665 ◽  
Author(s):  
Takashi Kubo

Recently, long-lived, organic radical species have attracted much attention from chemists and material scientists because of their unique electronic properties derived from their magnetic spin and singly occupied molecular orbitals. Most stable and persistent organic radicals are heteroatom-centered radicals, whereas carbon-centered radicals are generally very reactive and therefore have had limited applications. Because the physical properties of carbon-centered radicals depend predominantly on the topology of the π-electron array, the development of new carbon-centered radicals is key to new basic molecular skeletons that promise novel and diverse applications of spin materials. This account summarizes our recent studies on the development of novel carbon-centered radicals, including phenalenyl, fluorenyl, and triarylmethyl radicals.


2019 ◽  
Vol 25 (68) ◽  
pp. 15463-15471 ◽  
Author(s):  
Yohei Hattori ◽  
Evripidis Michail ◽  
Alexander Schmiedel ◽  
Michael Moos ◽  
Marco Holzapfel ◽  
...  

1962 ◽  
Vol 84 (7) ◽  
pp. 1132-1134 ◽  
Author(s):  
Henry. Judeikis ◽  
Daniel. Kivelson

2015 ◽  
Vol 49 (3) ◽  
pp. 236-243
Author(s):  
A. Boutier-Pischon ◽  
F. Auger ◽  
J.-M. Noël ◽  
A. Almario ◽  
Y.-M. Frapart

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