Induced Fit of Crown Cavity to Ammonium Ion Guests and Photoinduced Intracavity Reactions: Cold Gas-Phase Spectroscopy of Dibenzo-18-Crown-6 Complexes with NH4+, CH3NH3+, and CH3CH2NH3+

2020 ◽  
Vol 124 (16) ◽  
pp. 3228-3241 ◽  
Author(s):  
Mayuko Kubo ◽  
Motoki Kida ◽  
Satoru Muramatsu ◽  
Yoshiya Inokuchi
Author(s):  
Ryosuke Goda ◽  
Saya Kanazawa ◽  
Shiori Machida ◽  
Satoru Muramatsu ◽  
Yoshiya Inokuchi

1988 ◽  
Vol 152 (1) ◽  
pp. 87-93 ◽  
Author(s):  
K. McMillan ◽  
D. Bender ◽  
M. Eliades ◽  
D. Danzeiser ◽  
B.A. Wofford ◽  
...  

2017 ◽  
Vol 89 (9) ◽  
pp. 1349-1357 ◽  
Author(s):  
Jasper Wattjes ◽  
Baptiste Schindler ◽  
Stéphane Trombotto ◽  
Laurent David ◽  
Bruno M. Moerschbacher ◽  
...  

AbstractWe propose a novel, bi-dimensional analysis of partially N-acetylated chitosan oligosaccharides based on gas phase Infra-Red spectroscopy integrated to mass spectrometry (MS). By providing simultaneously MS and IR fingerprints, this approach combines the advantages of MS with the refined structural detail offered by gas phase spectroscopy and provides robust signatures for the rapid discrimination of the patterns of N-acetylation. Four mono-N-deacetylated and two doubly-N-deacetylated chitosan tetramer standards with well-defined patterns of acetylation were produced and analyzed by IR integrated to MS. We show that each sequence displays a unique combination of MS and IR fingerprints, thus offering a rapid diagnostic for the pattern of acetylation without the need for reducing end labeling.


2015 ◽  
Vol 17 (39) ◽  
pp. 25809-25821 ◽  
Author(s):  
Aude Bouchet ◽  
Johanna Klyne ◽  
Giovanni Piani ◽  
Otto Dopfer ◽  
Anne Zehnacker

The effects of ionisation and protonation on the geometric and electronic structure of a prototypical aromatic amino-alcohol with two chiral centres are revealed by IR and UV spectroscopy.


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