Ruthenium(II) Tris(2,2′-bipyridyl) Complex Incorporated in UiO-67 as Photoredox Catalyst

2018 ◽  
Vol 122 (51) ◽  
pp. 29190-29199 ◽  
Author(s):  
Andrea Santiago-Portillo ◽  
Herme G. Baldoví ◽  
Esther Carbonell ◽  
Sergio Navalón ◽  
Mercedes Álvaro ◽  
...  
Keyword(s):  
Bipyridyl Complex

scholarly journals Fluorescence properties of the Ga(III)-bipyridyl complex in aqueous solution.

1998 ◽  
Vol 47 (9) ◽  
pp. 605-612 ◽  
Author(s):  
Kunihiro WATANABE ◽  
Satoshi ABE ◽  
Masayuki ITAGAKI
Keyword(s):  
Aqueous Solution ◽  
Fluorescence Properties ◽  
Bipyridyl Complex

High nuclease activity of a copper(II)-bipyridyl complex containing cytosine pendants

2010 ◽  
Vol 63 (14-16) ◽  
pp. 2440-2449 ◽  
Author(s):  
Jin-Tao Wang ◽  
Xiao-Hui Zheng ◽  
Liang-Nian Ji ◽  
Zong-Wan Mao
Keyword(s):  
Nuclease Activity ◽  
Bipyridyl Complex

Direct photo-induced DNA strand scission by a ruthenium bipyridyl complex

2004 ◽  
Vol 98 (11) ◽  
pp. 1750-1756 ◽  
Author(s):  
Eylon Yavin ◽  
Eric D.A. Stemp ◽  
Lev Weiner ◽  
Irit Sagi ◽  
Rina Arad-Yellin ◽  
...  
Keyword(s):  
Strand Scission ◽  
Dna Strand ◽  
Bipyridyl Complex ◽  
Ruthenium Bipyridyl

scholarly journals The Interaction of Copper-Bipyridyl Complex with DNA and Cleavage to DNA

2004 ◽  
Vol 20 (8) ◽  
pp. 1127-1130 ◽  
Author(s):  
Zhou-Sheng YANG ◽  
Yan-Ling WANG ◽  
Guang-Chao ZHAO
Keyword(s):  
Bipyridyl Complex

Kinetics of the oxidation of Hg(I) by Fe(III)-2,2′-bipyridyl complex

1980 ◽  
Vol 42 (8) ◽  
pp. 1181-1184 ◽  
Author(s):  
P.V. Subba Rao ◽  
M. Suryanarayana ◽  
K.V. Subbaiah ◽  
P.S.N. Murty
Keyword(s):  
Kinetics Of ◽  
Bipyridyl Complex

Influence of Ru(II) Bipyridyl Complex on the Photocatalytic H2 Evolution over TiO2 Nanoparticles with Mesostructures

2008 ◽  
Vol 47-50 ◽  
pp. 825-828 ◽  
Author(s):  
Tian You Peng ◽  
Ding Ning Ke ◽  
Chun Wu ◽  
Cai Ping ◽  
Liang Ma ◽  
...  
Keyword(s):  
Visible Light ◽  
Dynamic Equilibrium ◽  
H2 Production ◽  
Electron Donors ◽  
H2 Evolution ◽  
Conjugation System ◽  
Antenna Effect ◽  
Dye Sensitized ◽  
Sensitization Process ◽  
Bipyridyl Complex

H2 production over dye-sensitized Pt/TiO2 nanoparticles with mesostructures under visible light was investigated by using methanol as electron donors. Three types of Ru(II) bipyridyl complexes, which can be attached to Pt/m-TiO2 with different linkage modes, show different photosensitization. The dye tightly linked with m-TiO2 has better durability but the lowest H2 evolution efficiency, whereas the loosely attached dyes possess higher H2 evolution efficiency and preferable durability. It seems that the dynamic equilibrium between the linkage of ground state dye with TiO2 and the divorce of oxidization state dye from the surfaces plays a crucial role in the photochemical behavior during photocatalyst sensitization process. The binuclear Ru(II) shows a better photosensitization in comparison with mono- nuclear Ru(II) dyes due to its large conjugation system and “antenna effect”, which, in turn, improve the visible light harvesting and electron transfer between the dye and TiO2.

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