Precise Synthesis of Poly(methyl methacrylate) Brush with Well-Controlled Stereoregularity Using a Surface-Initiated Living Anionic Polymerization Method

2016 ◽  
Vol 49 (6) ◽  
pp. 2071-2076 ◽  
Author(s):  
Masanao Sato ◽  
Tomoki Kato ◽  
Tomoyuki Ohishi ◽  
Ryohei Ishige ◽  
Noboru Ohta ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Anionic Polymerization ◽  
Living Anionic Polymerization ◽  
Poly Methyl Methacrylate ◽  
Polymerization Method

scholarly journals Synthesis and post-polymerization reaction of end-clickable stereoregular polymethacrylates via termination of stereospecific living anionic polymerization

2015 ◽  
Vol 6 (7) ◽  
pp. 1078-1087 ◽  
Author(s):  
Yasuhiro Kohsaka ◽  
Takashi Kurata ◽  
Kazuki Yamamoto ◽  
Shoya Ishihara ◽  
Tatsuki Kitayama
Keyword(s):  
Methyl Methacrylate ◽  
Anionic Polymerization ◽  
Polymerization Reaction ◽  
Living Anionic Polymerization ◽  
Poly Methyl Methacrylate ◽  
End Groups

Poly(methyl methacrylate)s with high stereoregularity and clickable end-groups were synthesized via terminating reactions with α-(halomethyl)acrylates in stereospecific living anionic polymerization.

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