Ring-Closing Metathesis and Ring-Opening Metathesis Polymerization toward Main-Chain Ferrocene-Containing Polymers

2018 ◽  
Vol 51 (22) ◽  
pp. 9131-9139 ◽  
Author(s):  
Ye Sha ◽  
Yudi Zhang ◽  
Tianyu Zhu ◽  
Shaobo Tan ◽  
Yujin Cha ◽  
...  
Keyword(s):  
Ring Opening ◽  
Main Chain ◽  
Ring Opening Metathesis Polymerization ◽  
Ring Closing Metathesis ◽  
Metathesis Polymerization

scholarly journals Grubbs’ and Schrock’s Catalysts, Ring Opening Metathesis Polymerization and Molecular Brushes—Synthesis, Characterization, Properties and Applications

Polymers ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 298 ◽  
Author(s):  
Ioannis Choinopoulos
Keyword(s):  
Metal Complexes ◽  
Ring Opening ◽  
Main Chain ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Molecular Brushes

In this review, molecular brushes and other macromolecular architectures bearing a bottlebrush segment where the main chain is synthesized by ring opening metathesis polymerization (ROMP) mediated by Mo or Ru metal complexes are considered. A brief review of metathesis and ROMP is presented in order to understand the problems and the solutions provided through the years. The synthetic strategies towards bottlebrush copolymers are demonstrated and each one discussed separately. The initiators/catalysts for the synthesis of the backbone with ROMP are discussed. Syntheses of molecular brushes are presented. The most interesting properties of the bottlebrushes are detailed. Finally, the applications studied by different groups are presented.

Main-Chain Calix[4]arene Elastomers by Ring-Opening Metathesis Polymerization

2007 ◽  
Vol 40 (21) ◽  
pp. 7437-7440 ◽  
Author(s):  
Yong Yang ◽  
Timothy M. Swager
Keyword(s):  
Ring Opening ◽  
Main Chain ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization

Crosslinked dendronized polyols as a general approach to brighter and more stable fluorophores

2016 ◽  
Vol 52 (19) ◽  
pp. 3781-3784 ◽  
Author(s):  
Ying Li ◽  
Yugang Bai ◽  
Nan Zheng ◽  
Yang Liu ◽  
Gretchen A. Vincil ◽  
...  
Keyword(s):  
Ring Opening ◽  
Sequential Process ◽  
Chain Ring ◽  
Ring Opening Metathesis Polymerization ◽  
Ring Closing Metathesis ◽  
Metathesis Polymerization

Fluorescent, aqueous-soluble, crosslinked dendronized polyols (CDPs) are obtained through a sequential process involving ring-opening metathesis polymerization (ROMP), intra-chain ring-closing metathesis (RCM), and hydrolysis.

SBA-15 Immobilized Ruthenium Carbenes as Catalysts for Ring Closing Metathesis and Ring Opening Metathesis Polymerization

2009 ◽  
Vol 53 (3-4) ◽  
pp. 200-209 ◽  
Author(s):  
David Bek ◽  
Naděžda Žilková ◽  
Jiří Dědeček ◽  
Jan Sedláček ◽  
Hynek Balcar
Keyword(s):  
Ring Opening ◽  
Ring Opening Metathesis Polymerization ◽  
Ring Closing Metathesis ◽  
Metathesis Polymerization ◽  
Ruthenium Carbenes

An entropy-driven ring-opening metathesis polymerization approach towards main-chain liquid crystalline polymers

2016 ◽  
Vol 7 (33) ◽  
pp. 5265-5272 ◽  
Author(s):  
Lin-Lin Deng ◽  
Ling-Xiang Guo ◽  
Bao-Ping Lin ◽  
Xue-Qin Zhang ◽  
Ying Sun ◽  
...  
Keyword(s):  
Ring Opening ◽  
Liquid Crystalline ◽  
Main Chain ◽  
Liquid Crystalline Polymers ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Crystalline Polymers ◽  
First Time

In this manuscript, an entropy-driven ring-opening metathesis polymerization (ED-ROMP) approach is applied for the first time in producing main-chain liquid crystalline polymers by polymerizing a macrocyclic olefin monomer.

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