Light-Promoted Transfer of an Iridium Hydride in Alkyl Ether Cleavage

2021 ◽  
Author(s):  
Caleb D. Fast ◽  
Nathan D. Schley
Keyword(s):  
Alkyl Ether ◽  
Ether Cleavage

scholarly journals Multiple Mechanisms Mapped in Aryl Alkyl Ether Cleavage via Aqueous Electrocatalytic Hydrogenation over Skeletal Nickel

2020 ◽  
Vol 142 (8) ◽  
pp. 4037-4050 ◽  
Author(s):  
Yuting Zhou ◽  
Grace E. Klinger ◽  
Eric L. Hegg ◽  
Christopher M. Saffron ◽  
James E. Jackson
Keyword(s):  
Alkyl Ether ◽  
Electrocatalytic Hydrogenation ◽  
Ether Cleavage ◽  
Skeletal Nickel

LAH Aryl Alkyl Ether Cleavage of BINOL Derivatives.

ChemInform ◽  
2005 ◽  
Vol 36 (18) ◽  
Author(s):  
Walter E. Kowtoniuk ◽  
Darren K. MacFarland
Keyword(s):  
Alkyl Ether ◽  
Ether Cleavage

Selective alkyl ether cleavage by cationic bis(phosphine)iridium complexes

2019 ◽  
Vol 17 (7) ◽  
pp. 1744-1748 ◽  
Author(s):  
Caleb A. H. Jones ◽  
Nathan D. Schley
Keyword(s):  
Functional Groups ◽  
Alkyl Ether ◽  
Iridium Complexes ◽  
Ether Cleavage ◽  
Mild Conditions

Simple cationic bis(phosphine)iridium complexes are shown to be highly selective catalysts for ether cleavage with silanes. Benzylic ethers can be cleaved under mild conditions in the presence of reductively-labile functional groups.

LAH aryl alkyl ether cleavage of BINOL derivatives

2005 ◽  
Vol 46 (3) ◽  
pp. 451-453 ◽  
Author(s):  
Walter E. Kowtoniuk ◽  
Darren K. MacFarland
Keyword(s):  
Alkyl Ether ◽  
Ether Cleavage

Boron insertion into alkyl ether bonds via zinc/nickel tandem catalysis

Science ◽  
2021 ◽  
Vol 372 (6538) ◽  
pp. 175-182
Author(s):  
Hairong Lyu ◽  
Ilia Kevlishvili ◽  
Xuan Yu ◽  
Peng Liu ◽  
Guangbin Dong
Keyword(s):  
Nickel Catalyst ◽  
Bioactive Compounds ◽  
Cyclic Ethers ◽  
Alkyl Ether ◽  
Tandem Catalysis ◽  
Mechanistic Studies ◽  
Alkyl Ethers ◽  
Nitrogen Substitution ◽  
Zinc Nickel

Mild methods to cleave the carbon-oxygen (C−O) bond in alkyl ethers could simplify chemical syntheses through the elaboration of these robust, readily available precursors. Here we report that dibromoboranes react with alkyl ethers in the presence of a nickel catalyst and zinc reductant to insert boron into the C−O bond. Subsequent reactivity can effect oxygen-to-nitrogen substitution or one-carbon homologation of cyclic ethers and more broadly streamline preparation of bioactive compounds. Mechanistic studies reveal a cleavage-then-rebound pathway via zinc/nickel tandem catalysis.

scholarly journals Synthetic Alkyl-Ether-lipid promotes TRPV2 Channel trafficking trough PI3K/Akt-Girdin Axis in cancer cells and increases mammary tumor volume

Cell Calcium ◽  
2021 ◽  
pp. 102435
Author(s):  
Maxime Guéguinou ◽  
Romain Felix ◽  
Séverine Marionneau-Lambot ◽  
Thibault Oullier ◽  
Aubin Penna ◽  
...  
Keyword(s):  
Cancer Cells ◽  
Mammary Tumor ◽  
Tumor Volume ◽  
Ether Lipid ◽  
Alkyl Ether ◽  
Channel Trafficking

Efficient Alkyl Ether Synthesis via Palladium-Catalyzed, Picolinamide-Directed Alkoxylation of Unactivated C(sp3)–H and C(sp2)–H Bonds at Remote Positions

2012 ◽  
Vol 134 (17) ◽  
pp. 7313-7316 ◽  
Author(s):  
Shu-Yu Zhang ◽  
Gang He ◽  
Yingsheng Zhao ◽  
Kiwan Wright ◽  
William A. Nack ◽  
...  
Keyword(s):  
Alkyl Ether ◽  
Palladium Catalyzed ◽  
Ether Synthesis

scholarly journals Ether Cleavage Re-Investigated: Elucidating the Mechanism of BBr3-Facilitated Demethylation of Aryl Methyl Ethers

2015 ◽  
Vol 2015 (34) ◽  
pp. 7460-7467 ◽  
Author(s):  
Talon M. Kosak ◽  
Heidi A. Conrad ◽  
Andrew L. Korich ◽  
Richard L. Lord
Keyword(s):  
Ether Cleavage ◽  
Aryl Methyl
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