scholarly journals Reactions of an Osmium(IV)-Hydroxo Complex with Amino-Boranes: Formation of Boroxide Derivatives

2018 ◽  
Vol 38 (2) ◽  
pp. 310-318 ◽  
Author(s):  
Antonio Antiñolo ◽  
Miguel A. Esteruelas ◽  
Cristina García-Yebra ◽  
Jaime Martín ◽  
Enrique Oñate ◽  
...  
Keyword(s):  
Hydroxo Complex

scholarly journals Insertion of Unsaturated C–C Bonds into the O–H Bond of an Iridium(III)-Hydroxo Complex: Formation of Phosphorescent Emitters with an Asymmetrical β-Diketonate Ligand

2020 ◽  
Vol 59 (21) ◽  
pp. 15877-15887
Author(s):  
Pierre-Luc T. Boudreault ◽  
Miguel A. Esteruelas ◽  
Ana M. López ◽  
Enrique Oñate ◽  
Esther Raga ◽  
...  
Keyword(s):  
Complex Formation ◽  
Hydroxo Complex

scholarly journals Oxidation of Naphthalene with a Manganese(IV) Bis(hydroxo) Complex in the Presence of Acid

2018 ◽  
Vol 130 (26) ◽  
pp. 7890-7894
Author(s):  
Donghyun Jeong ◽  
James J. Yan ◽  
Hyeonju Noh ◽  
Britt Hedman ◽  
Keith O. Hodgson ◽  
...  
Keyword(s):  
Hydroxo Complex

Hydrogen ion-selective electrode based on an iron-hydroxo-complex

1986 ◽  
Vol 323 (2) ◽  
pp. 142-144 ◽  
Author(s):  
Shin-ichi Wakida ◽  
Takashi Tanaka ◽  
Akinori Kawahara ◽  
Kazuo Hiiro
Keyword(s):  
Hydroxo Complex ◽  
Hydrogen Ion ◽  
Ion Selective Electrode ◽  
Selective Electrode

Simulation of the isomerization of an anionic hydroxo complex of rhodium(V)

2005 ◽  
Vol 15 (2) ◽  
pp. 81-83 ◽  
Author(s):  
Aleksei V. Avdei ◽  
Aleksandr Yu. Ermilov ◽  
Vladimir D. Dolzhenko ◽  
Yurii M. Kiselev
Keyword(s):  
Hydroxo Complex

scholarly journals Oxidation of Naphthalene with a Manganese(IV) Bis(hydroxo) Complex in the Presence of Acid

2018 ◽  
Vol 57 (26) ◽  
pp. 7764-7768 ◽  
Author(s):  
Donghyun Jeong ◽  
James J. Yan ◽  
Hyeonju Noh ◽  
Britt Hedman ◽  
Keith O. Hodgson ◽  
...  
Keyword(s):  
Hydroxo Complex

Reactions of acyl phosphates. Base hydrolysis of [Co(NH3)5OPO3COCH3]+ and the metal hydroxide promoted hydrolysis of acetyl phenyl phosphate

1981 ◽  
Vol 34 (8) ◽  
pp. 1769 ◽  
Author(s):  
DA Buckingham ◽  
CR Clark
Keyword(s):  
Hydroxo Complex ◽  
Metal Hydroxide ◽  
Base Hydrolysis ◽  
Acetyl Phosphate ◽  
Carbonyl Carbon ◽  
Phenyl Phosphate ◽  
Hydrolysis Of ◽  
Oxygen Bond

Tracer 18O studies have established that base hydrolysis of coordinated acetyl phosphate in [(NH3)5Co-OPO3COCH3]+ (kOH 0.53 mol-1 dm3 s-1, 25°C, I 1.0 NaClO4) proceeds with exclusive carbon-oxygen bond fission. The hydrolysis of acetyl phenyl phosphate monoanion is significantly catalysed by the exchange-inert hydroxo complex [(NH3)5Co-OH]2+ (kMOH 2.9 × 10-2 mol-1 dm3 s-1, 25°) which operates through a nucleophilic pathway involving attack at carbonyl carbon.

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