Oxidative Rearrangement of MIDA (N-Methyliminodiacetic Acid) Boronates: Mechanistic Insights and Synthetic Applications

2021 ◽  
Author(s):  
Sherif J. Kaldas ◽  
Chieh-Hung Tien ◽  
Gabriel dos Passos Gomes ◽  
Stephanie Meyer ◽  
Martynas Sirvinskas ◽  
...  
Keyword(s):  
Oxidative Rearrangement ◽  
Methyliminodiacetic Acid

Electroanalytical chemistry of vanadium complexes. Comparison of the voltammetric features of amavadine with those of the vanadium complexes with iminodiacetic acid and methyliminodiacetic acid

1989 ◽  
Vol 54 (1) ◽  
pp. 53-63 ◽  
Author(s):  
Roland Meier ◽  
Harald Frank ◽  
Reinhard Kirmse ◽  
Reiner Salzer ◽  
Joachim Stach ◽  
...  
Keyword(s):  
Iminodiacetic Acid ◽  
Vanadium Complexes ◽  
Reduction Mechanism ◽  
Reversible Process ◽  
Electroanalytical Chemistry ◽  
Probable Explanation ◽  
Chemical Sense ◽  
Ece Mechanism ◽  
Methyliminodiacetic Acid

The voltammetric behaviour of amavadine (AV) was found to be considerably different from that of the complexes of VO2+ with methyliminodiacetic acid (MIDA) and iminodiacetic acid (IDA). To get an insight in the rather complicated reduction mechanism of the latter complexes the reductions of V(III) (MIDA) and V(III) (IDA) have been studied for comparison. The species V(III) (MIDA)2 and V(III) (IDA)2 are reduced to the appropriate V(II) complexes in a chemically reversible process. VO(MIDA)2 and VO(IDA)2 are reduced to the same complexes via an ECE mechanism. The investigation of the electroreduction of AV shows that this process is not reversible in the chemical sense. As a probable explanation, the conclusion was drawn that AV and the usual V(IV)O-iminocarboxylato complexes differ in their structures.

A New Oxidative Rearrangement of a Phorbol Derivative

1995 ◽  
Vol 58 (2) ◽  
pp. 284-287 ◽  
Author(s):  
Giovanni Appendino ◽  
Gian Paolo Carello ◽  
Renata Enriú ◽  
Jasmin Jakupovic
Keyword(s):  
Oxidative Rearrangement

Oxidative Rearrangement Processes in the Biosynthesis of Gilvocarcin V

2004 ◽  
Vol 126 (39) ◽  
pp. 12262-12263 ◽  
Author(s):  
Tao Liu ◽  
Carsten Fischer ◽  
Claus Beninga ◽  
Jürgen Rohr
Keyword(s):  
Oxidative Rearrangement ◽  
Gilvocarcin V ◽  
Rearrangement Processes

scholarly journals Microwave-mediated synthesis of N-methyliminodiacetic acid (MIDA) boronates

Tetrahedron ◽  
2014 ◽  
Vol 70 (47) ◽  
pp. 9125-9131 ◽  
Author(s):  
Adam J. Close ◽  
Paul Kemmitt ◽  
Matthew K. Emmerson ◽  
John Spencer
Keyword(s):  
Methyliminodiacetic Acid
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