Kinetics and mechanisms of oxidation of organic compounds by silver(II) species. Part VI: Iminodiacetic acid andN-methyliminodiacetic acid

1982 ◽  
Vol 14 (9) ◽  
pp. 1017-1032 ◽  
Author(s):  
Claudio Baiocchi ◽  
Giuseppe Bovio ◽  
Edoardo Mentasti
Keyword(s):  
Organic Compounds ◽  
Iminodiacetic Acid ◽  
Oxidation Of Organic Compounds ◽  
Methyliminodiacetic Acid

Electroanalytical chemistry of vanadium complexes. Comparison of the voltammetric features of amavadine with those of the vanadium complexes with iminodiacetic acid and methyliminodiacetic acid

1989 ◽  
Vol 54 (1) ◽  
pp. 53-63 ◽  
Author(s):  
Roland Meier ◽  
Harald Frank ◽  
Reinhard Kirmse ◽  
Reiner Salzer ◽  
Joachim Stach ◽  
...  
Keyword(s):  
Iminodiacetic Acid ◽  
Vanadium Complexes ◽  
Reduction Mechanism ◽  
Reversible Process ◽  
Electroanalytical Chemistry ◽  
Probable Explanation ◽  
Chemical Sense ◽  
Ece Mechanism ◽  
Methyliminodiacetic Acid

The voltammetric behaviour of amavadine (AV) was found to be considerably different from that of the complexes of VO2+ with methyliminodiacetic acid (MIDA) and iminodiacetic acid (IDA). To get an insight in the rather complicated reduction mechanism of the latter complexes the reductions of V(III) (MIDA) and V(III) (IDA) have been studied for comparison. The species V(III) (MIDA)2 and V(III) (IDA)2 are reduced to the appropriate V(II) complexes in a chemically reversible process. VO(MIDA)2 and VO(IDA)2 are reduced to the same complexes via an ECE mechanism. The investigation of the electroreduction of AV shows that this process is not reversible in the chemical sense. As a probable explanation, the conclusion was drawn that AV and the usual V(IV)O-iminocarboxylato complexes differ in their structures.

scholarly journals Efficient, Solvent-Free Oxidation of Organic Compounds with Potassium Dichromate in the Presence of Lewis Acids

Molecules ◽  
2001 ◽  
Vol 6 (11) ◽  
pp. 900-908 ◽  
Author(s):  
Iraj Mohammadpoor-Baltork ◽  
Majid Sadeghi ◽  
Abol-Hassan Adibi
Keyword(s):  
Organic Compounds ◽  
Lewis Acids ◽  
Potassium Dichromate ◽  
Solvent Free ◽  
Oxidation Of Organic Compounds ◽  
Free Oxidation
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