Highly Efficient Synthesis of Chiral α-CF3 Amines via Rh-Catalyzed Asymmetric Hydrogenation

2015 ◽  
Vol 17 (5) ◽  
pp. 1154-1156 ◽  
Author(s):  
Jun Jiang ◽  
Wenxin Lu ◽  
Hui Lv ◽  
Xumu Zhang
2017 ◽  
Vol 53 (66) ◽  
pp. 9258-9261 ◽  
Author(s):  
Tao Zhang ◽  
Jun Jiang ◽  
Lin Yao ◽  
Huiling Geng ◽  
Xumu Zhang

A series of chiral aromatic ketones were achieved with excellent enantioselectivities via Rh–ZhaoPhos catalyzed asymmetric hydrogenation of β,β-disubstituted enones.


2019 ◽  
Vol 17 (4) ◽  
pp. 785-788 ◽  
Author(s):  
Lin Tao ◽  
Congcong Yin ◽  
Xiu-Qin Dong ◽  
Xumu Zhang

A highly efficient Ir-catalyzed asymmetric hydrogenation of prochiral β-keto sulfones was successfully developed, affording a series of chiral β-hydroxy sulfones with excellent results (up to >99% conversion, 99% yield, >99% ee, and 20 000 TON).


2004 ◽  
Vol 126 (32) ◽  
pp. 9918-9919 ◽  
Author(s):  
Yi Hsiao ◽  
Nelo R. Rivera ◽  
Thorsten Rosner ◽  
Shane W. Krska ◽  
Eugenia Njolito ◽  
...  

2014 ◽  
Vol 34 (1) ◽  
pp. 243-250
Author(s):  
Jianghong DING ◽  
Le XU ◽  
Hao XU ◽  
Haihong WU ◽  
Yueming LIU ◽  
...  

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