Stereoselective Allylic Alkylation of 1-Pyrroline-5-carboxylic Esters via a Pd/Cu Dual Catalysis

2018 ◽  
Vol 20 (20) ◽  
pp. 6564-6568 ◽  
Author(s):  
Penglin Liu ◽  
Xiaohong Huo ◽  
Bowen Li ◽  
Rui He ◽  
Jiacheng Zhang ◽  
...  
Keyword(s):  
Allylic Alkylation ◽  
Dual Catalysis ◽  
Carboxylic Esters

Stereoselective and Site-Specific Allylic Alkylation of Amino Acids and Small Peptides via a Pd/Cu Dual Catalysis

2017 ◽  
Vol 139 (29) ◽  
pp. 9819-9822 ◽  
Author(s):  
Xiaohong Huo ◽  
Rui He ◽  
Jingke Fu ◽  
Jiacheng Zhang ◽  
Guoqiang Yang ◽  
...  
Keyword(s):  
Amino Acids ◽  
Allylic Alkylation ◽  
Small Peptides ◽  
Site Specific ◽  
Dual Catalysis

Relay Rh(ii)/Pd(0) dual catalysis: synthesis of α-quaternary β-keto-esters via a [1,2]-sigmatropic rearrangement/allylic alkylation cascade of α-diazo tertiary alcohols

2020 ◽  
Vol 56 (5) ◽  
pp. 782-785 ◽  
Author(s):  
Xian-Xu Wang ◽  
Xiao-Yan Huang ◽  
Sen-Hao Lei ◽  
Fang Yang ◽  
Jin-Ming Gao ◽  
...  
Keyword(s):  
Palladium Catalysts ◽  
Sigmatropic Rearrangement ◽  
Allylic Alkylation ◽  
Tertiary Alcohols ◽  
Keto Esters ◽  
Dual Catalysis

Rhodium and palladium catalysts cooperated efficiently to promote domino [1,2]-sigmatropic rearrangement/allylic alkylation of α-diazo tertiary alcohols to access α-quaternary β-keto-esters.

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