Iridium-Catalyzed Enantioselective Allyl–Allyl Cross-Coupling of Racemic Allylic Alcohols with Allylboronates

2018 ◽  
Vol 20 (24) ◽  
pp. 8035-8038 ◽  
Author(s):  
Yu Zheng ◽  
Bei-Bei Yue ◽  
Kun Wei ◽  
Yu-Rong Yang
Keyword(s):  
Cross Coupling ◽  
Allylic Alcohols

ChemInform Abstract: Complex Allylation by the Direct Cross-Coupling of Imines with Unactivated Allylic Alcohols.

ChemInform ◽  
2009 ◽  
Vol 40 (36) ◽  
Author(s):  
Masayuki Takahashi ◽  
Martin McLaughlin ◽  
Glenn C. Micalizio
Keyword(s):  
Cross Coupling ◽  
Allylic Alcohols ◽  
Direct Cross

ChemInform Abstract: Dehydrative Cross-Coupling Reactions of Allylic Alcohols with Olefins.

ChemInform ◽  
2015 ◽  
Vol 46 (8) ◽  
pp. no-no
Author(s):  
Yasemin Gumrukcu ◽  
Bas de Bruin ◽  
Joost N. H. Reek
Keyword(s):  
Cross Coupling ◽  
Allylic Alcohols ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

scholarly journals Stereoselective Cross-Coupling between Allylic Alcohols and Aldimines

2009 ◽  
Vol 11 (14) ◽  
pp. 3132-3134 ◽  
Author(s):  
Ivan L. Lysenko ◽  
Hyung Goo Lee ◽  
Jin Kun Cha
Keyword(s):  
Cross Coupling ◽  
Allylic Alcohols

Cp*Rh(iii)-catalyzed C(sp3)–H alkylation of 8-methylquinolines in aqueous media

2017 ◽  
Vol 53 (21) ◽  
pp. 3006-3009 ◽  
Author(s):  
Saegun Kim ◽  
Sangil Han ◽  
Jihye Park ◽  
Satyasheel Sharma ◽  
Neeraj Kumar Mishra ◽  
...  
Keyword(s):  
Aqueous Media ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Allylic Alcohols ◽  
Efficient Approach ◽  
Cross Coupling Reaction ◽  
The Cross

A mild and efficient approach for the cross-coupling reaction of 8-methylquinolines with a range of allylic alcohols in water as a solvent under rhodium(iii) catalysis is described.

Sequential O-Arylation/Lanthanide(III)-Catalyzed [3,3]-Sigmatropic Rearrangement of Bromo-Substituted Allylic Alcohols

Synlett ◽  
2017 ◽  
Vol 28 (20) ◽  
pp. 2865-2870 ◽  
Author(s):  
Timothy Ramadhar ◽  
Jun-ichi Kawakami ◽  
Robert Batey
Keyword(s):  
Claisen Rearrangement ◽  
Cross Coupling ◽  
Sigmatropic Rearrangement ◽  
Mitsunobu Reaction ◽  
Allylic Alcohols ◽  
Aryl Ether ◽  
Claisen Rearrangements ◽  
Snar Reaction ◽  
Aryl Ethers

Lanthanide(III)-catalyzed aryl-Claisen rearrangement of substrates bearing halo-substituted allyl groups, specifically 2-bromoallyl aryl ethers, afford ortho-2-bromoallylphenols. Aryl ether substrates were synthesized from brominated allylic alcohols via Mitsunobu reaction, Cu(II)-catalyzed arylation using potassium aryltrifluoroborate salts, or SNAr reaction. Aryl-Claisen rearrangements proceeded in moderate to excellent yields using Eu(III) catalysis. The alkenylbromide functionality remains intact, illustrating the compatibility of synthetically important alkenylhalides during C–O/C–C σ-bond migration processes. Subsequent derivatization of the ortho-2-bromoallylphenol products through O-alkylation or C-arylation/alkenylation via Suzuki–Miyaura cross-coupling demonstrate the potential to access densely-functionalized molecules.

Carbon-Carbon Bond Formation: Palladium-Catalyzed Oxidative Cross-Coupling of N-Tosylhydrazones with Allylic Alcohols

2012 ◽  
Vol 18 (34) ◽  
pp. 10497-10500 ◽  
Author(s):  
Huoji Chen ◽  
Li Huang ◽  
Wei Fu ◽  
Xiaohang Liu ◽  
Huanfeng Jiang
Keyword(s):  
Bond Formation ◽  
Cross Coupling ◽  
Allylic Alcohols ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Palladium Catalyzed
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